Removable Protective Coating for Dust-Free Catalyst Handling

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Solution Overview

Problem

Catalysts used in the chemical industry, such as those for producing maleic anhydride, suffer from significant dust formation due to abrasion and attrition, leading to exposure risks for personnel, equipment damage, and operational inefficiencies, particularly due to the presence of toxic materials like Cr(VI) and vanadyl pyrophosphate, which complicates handling and reactor performance.

Innovation Solution

A stabilized catalyst mould is created by applying a protective organic binder coating to the outer surface of the catalyst body, enhancing abrasion and attrition resistance, minimizing dust formation, and allowing easy removal without affecting the catalytically active material's performance or leaving residues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a catalyst mould is used for producing maleic anhydride, then catalytic performance is achieved, but dust formation occurs due to abrasion and attrition

Engineering Contradiction:
Improvecatalytic performanceVSAvoiddust formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A protective coating layer is applied to the surface of the catalyst mould, forming a thin film that prevents dust formation during handling while preserving the catalytic activity. The coating acts as a protective shell that reduces abrasion and attrition of the catalyst material.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The catalyst mould is created as a composite structure combining the catalytically active material with a binding agent or protective coating. This composite approach maintains the catalytic functionality while reducing dust formation through improved mechanical stability.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If catalyst moulds are mechanically stressed during handling, then catalyst loading and transportation are enabled, but heavy dust formation occurs due to abrasion and attrition

Engineering Contradiction:
Improvehandling capabilityVSAvoiddust formation
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The protective coating on the catalyst mould surface acts as a flexible shell that withstands mechanical stress during handling, transportation, and loading operations without causing significant dust formation. The coating maintains integrity under compression and mechanical agitation.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The protective coating is applied beforehand to cushion the catalyst material against mechanical stress during subsequent handling operations. This pre-protection prevents dust formation during transportation and loading by absorbing mechanical energy before it reaches the catalyst particles.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Object-affected harmful factors

If extensive personal protection equipment and vacuum systems are used, then exposure to catalyst dust is reduced, but handling costs and complexity increase

Engineering Contradiction:
Improvepersonnel exposureVSAvoidprotection system complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The harmful dust formation is extracted or eliminated at the source by applying the protective coating to the catalyst mould. This prevents dust generation during handling, thereby eliminating the need for extensive personal protection equipment and vacuum systems.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The protective coating converts the potentially harmful catalytic material into a dust-free form during handling. The same material that could cause exposure risks is transformed into a stable, coated structure that eliminates dust formation, turning a harmful property into a beneficial one.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Productivity

If catalyst fines are present in reactor tubes, then catalyst loading is simplified, but pressure drop tolerance is exceeded requiring emptying and refilling

Engineering Contradiction:
Improveloading efficiencyVSAvoidpressure drop control
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The protective coating on catalyst moulds prevents the generation of fines during loading, ensuring that catalyst particles maintain their integrity. This keeps pressure drop within tolerance ranges and eliminates the need to empty and refill reactor tubes.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The protective coating is applied preliminarily to the catalyst moulds before loading into the reactor. This pre-protection ensures that during the loading process, no fines are generated that would exceed pressure drop tolerance, thereby maintaining productivity without requiring subsequent reactor emptying.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces dust formation during handling, improves catalyst durability, and maintains the catalytic performance and efficiency, while also simplifying reactor loading and reducing environmental exposure to toxic substances.

Implementation Method 1

an organic binder that has penetrated into the surface of a catalyst body made of catalyst material and that forms a protective layer together with the catalyst material present at the surface

Methodology Applied
Scientific EffectPenetration: Permeation

Implementation Method 2

forms a protective layer together with the catalyst material present at the surface of the catalyst body to thereby stabilize the outer surface

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS10252254B2Removable protective coating for the receipt of a dust free catalyst
Publication Date: 2019.04.09 CLARIANT INT LTD
  • US10252254B2 patent drawing
  • US10252254B2 patent drawing
  • US10252254B2 patent drawing

AI summary

The invention pertains to a stabilized catalyst mold comprising a catalyst body formed of a catalyst material, said catalyst material comprising a catalytically active material or a precursor material of the catalytically active material, characterized in that at least parts of the surface of the catalyst mold are provided with a protective coating comprising an organic binder. Further, the invention pertains to a method for obtaining a stabilized catalyst mold.