Insect Repellent-Polymer Gel for Extended Efficacy

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Solution Overview

Problem

Existing insect repellent materials face challenges such as short efficacy times due to evaporation, phase separation between insect repellents and polymers, and high processing temperatures that lead to vaporization and loss of insect repellents.

Innovation Solution

A composition comprising an insect repellent compound and a polymer that is miscible with the insect repellent at 23°C, allowing for high loading of insect repellent and formation of physical gels through simple dissolution methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of moving object

If traditional aerosol sprays or topical lotions are used for outdoor protection, then application is simple, but efficacy time is short due to evaporation

Engineering Contradiction:
Improveefficacy timeVSAvoidevaporation loss
Core Design Contradiction:
Duration of action of moving objectVSLoss of substance

Solution Approach 1:

The patent uses a porous polymer matrix that physically entraps the insect repellent substrate, allowing controlled release while preventing rapid evaporation. The porous structure provides high surface area for repellent loading while the polymer network restricts molecular mobility, extending efficacy duration.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention creates a composite material system combining polymer matrix with insect repellent substrate. This composite approach allows the polymer to provide structural integrity and controlled release properties while the repellent provides the active protective function, resolving the contradiction between simple application and extended efficacy.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If insect repellent is physically entrapped in polymeric material to increase efficacy time, then duration of protection is extended, but processing requires high temperatures that cause vaporization and loss of insect repellent

Engineering Contradiction:
Improveefficacy timeVSAvoidvaporization loss during processing
Core Design Contradiction:
Duration of action of moving objectVSLoss of substance

Solution Approach 1:

The patent employs low-temperature processing methods to form the polymer-insect repellent composite, avoiding the high temperatures that cause vaporization. By changing the processing temperature parameter from traditional high-temperature curing to low-temperature formation, the invention preserves the insect repellent substrate while achieving effective entrapment and extended release.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces thermal processing mechanisms with alternative formation methods that do not rely on high-temperature curing or crosslinking. This substitution allows the polymer matrix to be formed at temperatures below the flash point of the insect repellent, preventing vaporization loss during manufacturing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Quantity of substance

If high insect repellent loading is achieved in polymer systems, then repellency is enhanced, but phase separation occurs between insect repellent and polymer

Engineering Contradiction:
Improveinsect repellent loadingVSAvoidphase separation
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent uses carefully selected polymer matrices that act as compatible intermediaries between the insect repellent substrate and the final product. The polymer chemistry is designed to be miscible with the repellent at processing temperatures while providing physical entrapment at use conditions, preventing phase separation even at high loading concentrations.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention achieves homogeneous distribution of insect repellent throughout the polymer matrix by selecting polymers with compatible chemical properties and using low-temperature processing. This homogeneity prevents phase separation and ensures uniform repellent release, maintaining both high loading and compositional stability.

Inventive Principle:
Principle #33Homogeneity

4Ease of manufacture

If polymer melting is used to process insect repellent-infused materials, then product formation is achieved, but high temperatures cause vaporization and safety concerns

Engineering Contradiction:
Improveproduct formationVSAvoidprocessing temperature
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

Instead of melting the polymer and then adding the insect repellent (traditional approach), the invention inverts the sequence by first incorporating the insect repellent into the polymer matrix at low temperatures, then forming the final product. This inversion allows product formation without exposing the repellent to high temperatures, eliminating vaporization risks while maintaining manufacturing feasibility.

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves significant improvements in insect repellent loading, reduces processing temperatures, and extends the duration of insect repellent release, providing long-term protection against biting arthropods.

Implementation Method 1

a polymer that is miscible in the insect repellent compound at 23° C.

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

The insect repellent loading in a physical gel is maximized if the repellent acts as the gelling solvent. Therefore, the polymer and insect repellent must be miscible with one another.

Methodology Applied
Scientific EffectMiscibility:

Implementation Method 3

Physical gels are a miscible polymer and solvent system that exhibit a storage modulus greater than its loss modulus (G′′/G′=tan(δ)≤1) at a frequency of 1 Hz.

Methodology Applied
Scientific EffectGel formation: Gel

Implementation Method 4

Physical gels are a miscible polymer and solvent system that exhibit a storage modulus greater than its loss modulus

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 5

Physical gels give the added benefit of thermos-reversal properties through the formation and deformation of microcrystals at polymer chain entanglement junctions.

Methodology Applied
Scientific EffectThermos-reversal: Phase Change

Implementation Method 6

thermos-reversal properties through the formation and deformation of microcrystals at polymer chain entanglement junctions

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 7

Passively-controlled substrate release has most commonly been investigated for in vivo drug delivery systems through gelled polymer morphologies.

Methodology Applied
Scientific EffectPassive-controlled substrate release: Diffusion

Data Source

PatentUS20250024835A1Insect repellent-polymer gels
Publication Date: 2025.01.23 THE GOVERNMENT OF THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY DEPARTMENT OF HEALTH & HUMAN SERVICES
  • US20250024835A1 patent drawing
  • US20250024835A1 patent drawing
  • US20250024835A1 patent drawing

AI summary

Disclosed herein is a composition having an insect repellent compound and a polymer that is miscible in the insect repellent compound at 23° C. Also disclosed herein is a method of: providing an insect repellent compound, providing a polymer that is miscible in the insect repellent compound at 23° C., and dissolving the polymer in the insect repellent compound to form a composition.