Resettable Alloy BCT-FCC Dual Structure Grain Growth Prevention

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Solution Overview

Problem

Conventional self-healing and stress relief heat treatment mechanisms are ineffective in prolonging the lifespan of metals due to low diffusion coefficients and unintended grain growth, respectively, which reduces material strength.

Innovation Solution

A resettable alloy with a body-centered tetragonal (BCT)-face-centered cubic (FCC) dual structure, featuring a martensite phase matrix and selectively segregated austenite phase, undergoes a two-step heat treatment and resetting treatment to induce metastable reversible phase transformation, preventing grain growth and recovering initial microstructure and properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If stress relief heat treatment is applied to reduce residual stresses, then the lifespan of the material is increased, but grain growth and defect annihilation occur which rapidly decrease the strength of the material

Engineering Contradiction:
Improvelifespan of materialVSAvoidstrength of material
Core Design Contradiction:
Duration of action of stationary objectVSStrength

Solution Approach 1:

The invention applies a specific heat treatment parameter regime (temperature range of 200-450°C for 1-24 hours) that changes the thermal parameters to enable stress relief while preventing grain growth. This controlled parameter change allows the material to recover without the detrimental effects of conventional high-temperature stress relief treatments

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite microstructure consisting of recovered martensite phases and retained austenite phases. This composite structure at the micro level provides both the strength from the martensite and the ductility and damage tolerance from the austenite, resolving the contradiction between strength and lifespan

Inventive Principle:
Principle #40Composite materials

2Reliability

If self-healing mechanism is applied to close cracks by diffusion, then crack propagation is prevented, but the mechanism is highly unlikely to work in metals due to extremely low diffusion coefficients

Engineering Contradiction:
Improvecrack resistanceVSAvoidfeasibility of self-healing in metals
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention utilizes phase transition mechanisms (martensite-austenite transformation) as an alternative to diffusion-based self-healing. The phase transition occurs rapidly at relatively low temperatures and can accommodate crack closure and damage repair without requiring atomic diffusion, making it feasible for metal applications

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The invention replaces the chemical diffusion mechanism with a mechanical phase transformation mechanism. Instead of relying on atomic diffusion to close cracks, the material uses stress-induced phase transformations that can rapidly respond to and heal crack damage through mechanical means

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alloy can repetitively recover its initial performance and extend its lifespan by controlling microstructures through selective segregation and phase transformation, maintaining strength and preventing premature failure.

Implementation Method 1

the FCC phase is formed by selective segregation of component elements

Methodology Applied
Scientific EffectSelective segregation:

Implementation Method 2

can be reset through metastable reversible phase transformation

Methodology Applied
Scientific EffectPhase transformation: Phase Change

Implementation Method 3

grain boundary segregation enthalpy quantitatively indicative of grain boundary segregation tendency within materials

Methodology Applied
Scientific EffectGrain boundary segregation:

Data Source

PatentUS11447843B2Resettable alloys and manufacturing method for the same
Publication Date: 2022.09.20 SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION
  • US11447843B2 patent drawing
  • US11447843B2 patent drawing
  • US11447843B2 patent drawing

AI summary

A resettable alloy having a resetting mechanism introduced thereinto through simple resetting treatment, thereby prolonging the lifespan of materials, and a manufacturing method for the same are provided. The resettable alloy comprises a body-centered tetragonal(BCT)-face-centered cubic(FCC) dual structure comprising: BCT martensite phase matrix; and FCC austenite phase present within the matrix, wherein the FCC phase is formed by selective segregation of component elements and can be repetitively reset through metastable reversible phase transformation.