Resin Composition for Flexible Display Adhesion

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing adhesive resins for flexible display devices face challenges in maintaining reliability and durability, especially at high and low temperatures, and during folding or bending, due to issues with viscosity, adhesion, and flexibility.

Innovation Solution

A resin composition comprising a (meth)acrylate with a hydroxy group, a polymer with polyisoprene or polybutadiene as the main skeleton, and a urethane (meth)acrylate oligomer, which has a low glass transition temperature and high adhesion properties, allowing for excellent coating properties and stability at various temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If adhesive resin is used for flexible display devices, then adhesion is achieved, but reliability deteriorates at high and low temperatures and during folding

Engineering Contradiction:
Improveadhesive reliabilityVSAvoidtemperature stability
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the chemical composition parameters of the adhesive resin by incorporating specific components: a polymer with polyisoprene or polybutadiene main skeleton (providing flexibility and low glass transition temperature), a (meth)acrylate monomer with hydroxy group (enhancing adhesion), and controlling the glass transition temperature to be -50°C to 0°C. These parameter changes enable the adhesive to maintain reliability across temperature ranges and during folding operations.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If adhesive resin formulation is optimized for low glass transition temperature, then flexibility is improved, but viscosity control becomes difficult

Engineering Contradiction:
Improveglass transition temperatureVSAvoidviscosity control
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent uses a composite material system combining three key components: (1) a polymer with polyisoprene or polybutadiene main skeleton providing the base flexibility and low glass transition temperature, (2) a (meth)acrylate monomer with hydroxy group contributing to adhesion and viscosity control, and (3) additional (meth)acrylate monomers. This composite formulation achieves the desired glass transition temperature range (-50°C to 0°C) while maintaining controllable viscosity through the synergistic interaction of components.

Inventive Principle:
Principle #40Composite materials

3Reliability

If adhesive member is designed for high flexural adhesiveness, then folding reliability is improved, but adhesion strength may be compromised

Engineering Contradiction:
Improvefolding reliabilityVSAvoidadhesion strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies local quality by providing different functional properties at different molecular levels: the polymer backbone (polyisoprene/polybutadiene) provides flexibility and fold endurance, while the (meth)acrylate monomers with hydroxy groups provide strong chemical adhesion to substrates. This local differentiation of material properties within the same adhesive composition enables simultaneous achievement of high flexural adhesiveness and strong adhesion strength.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin composition forms an adhesive member with high flexibility and durability, ensuring reliable adhesion and stability at both high and low temperatures, even during repeated folding or bending, without the need for plasticizers or organic solvents, thus enhancing the operational reliability of flexible display devices.

Implementation Method 1

the resin composition may have a glass transition temperature in a range of about −50° C. to about 0° C. after the resin composition is cured

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 2

the resin composition may have a viscosity in a range of about 5 mPa·s to about 50 mPa·s at a temperature in a range of about 30° C. to about 50° C.

Methodology Applied
Scientific EffectViscosity:

Data Source

PatentUS12071500B2Resin composition, adhesive member, and display device including the same
Publication Date: 2024.08.27 SAMSUNG DISPLAY CO LTD
  • US12071500B2 patent drawing
  • US12071500B2 patent drawing
  • US12071500B2 patent drawing

AI summary

A resin composition may include a (meth)acrylate (A) comprising a hydroxy group and having a molecular weight of about 500 or less, and a polymer (B) comprising polyisoprene or polybutadiene as a main skeleton, having at least one radical reactive group in one molecule, and having a molecular weight in a range of about 2,000 to about 35,000, wherein the resin composition has a glass transition temperature in a range of about −50° C. to about 0° C. after the resin composition is cured, and the resin composition has a viscosity in a range of about 5 mPa·s to about 50 mPa·s at a temperature in a range of about 30° C. to about 50° C.