Resin-Coated Pigment Ink Composition for Intercolor Bleeding Control

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Solution Overview

Problem

Existing ink compositions face issues with intercolor bleeding when multiple inks of different hues are applied in layers, and the inclusion of certain amphoteric surfactants can compromise storage stability.

Innovation Solution

An ink composition containing a resin-coated pigment, a betaine compound with an alkyl group of 6 to 20 carbon atoms, and water, where the betaine compound is used to enhance the ink film, and the resin is cross-linked to prevent resin peeling and maintain stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a betaine compound with an alkyl group is added to suppress intercolor bleeding, then bleeding prevention is improved, but storage stability deteriorates due to interactions with resin-coated pigments

Engineering Contradiction:
Improveintercolor bleedingVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter of the betaine compound to 1000 or less, which fundamentally alters its interaction characteristics with resin-coated pigments. This parameter change allows the betaine compound to suppress intercolor bleeding through enhanced surface tension while minimizing harmful interactions that compromise storage stability, thus resolving the technical contradiction between bleeding prevention and storage stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system combining cross-linked resin-coated pigments with specific betaine compounds (molecular weight ≤1000). The cross-linked resin structure works synergistically with the betaine compound to maintain pigment coating integrity while enabling effective bleeding suppression, thereby achieving both improved bleeding prevention and maintained storage stability

Inventive Principle:
Principle #40Composite materials

2Reliability

If a cross-linked resin is used to coat pigments to maintain storage stability, then storage stability is improved, but intercolor bleeding suppression deteriorates

Engineering Contradiction:
Improvestorage stabilityVSAvoidintercolor bleeding
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The betaine compound acts as an intermediary substance between the cross-linked resin-coated pigment and the recording medium. It mediates the surface interactions to prevent intercolor bleeding while allowing the cross-linked resin to maintain its pigment coating, thus resolving the contradiction between storage stability and bleeding suppression

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses intercolor bleeding and maintains storage stability, ensuring excellent jettability and image quality, particularly suitable for inkjet inks.

Implementation Method 1

a resin-coated pigment in which at least a part of pigments is coated with a cross-linked resin

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Implementation Method 2

the ink composition further contains an anionic or amphoteric surfactant

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 3

an ink composition composed of at least a coloring material, an anionic resin emulsion, a water-soluble organic solvent, and water, and a reaction solution including a reactant which causes aggregate in a case of being in contact with the aqueous ink composition and a cationic resin emulsion, in which the ink composition further contains an anionic or amphoteric surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS12624237B2Ink composition, ink set, and image forming method
Publication Date: 2026.05.12 FUJIFILM CORP
  • US12624237B2 patent drawing
  • US12624237B2 patent drawing
  • US12624237B2 patent drawing

AI summary

An ink composition includes a resin-coated pigment in which at least a part of pigments is coated with a cross-linked resin, a betaine compound (1) represented by Formula (1), and water. R1 represents an alkyl group having 6 to 20 carbon atoms, R2 and R3 each independently represent a chain hydrocarbon group having 1 to 3 carbon atoms, L1 represents a single bond or a divalent linking group, L2 represents a divalent linking group, and A-represents a —SO3− group or a —COO− group.