Resin-Coated Recording Material for Laser Printing

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Solution Overview

Problem

Current recording materials for electrophotographic processes, particularly in laser printing, face issues with toner fixation, light and ozone stability, and stackability, especially when used for producing photo books, which require improved color density and handling in printing devices.

Innovation Solution

A recording material with a raw paper coated on both sides by a synthetic resin and featuring a toner-absorbing layer composed of a polymer combination of ethylene-acrylic acid copolymer, carboxylated acrylic copolymer, and another polymer with specific melting points, along with an antistatic agent, to enhance toner reception and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If coated satin papers are used for electrophotographic printing to produce photo books, then both-sided printing capability is achieved, but image quality deteriorates in terms of color density, light and ozone stability

Engineering Contradiction:
Improveboth-sided printing capabilityVSAvoidimage quality, color density, light and ozone stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies composite materials by combining multiple polymer components in the toner-absorbing layer: a thermoplastic polymer (polyethylene or polypropylene), a polymer with carboxyl groups (for toner adhesion), and an antistatic agent. This composite structure enables both-sided printing capability while maintaining high image quality, color density, and stability against light and ozone, resolving the contradiction between versatility and reliability.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional resin-coated papers are used, then basic printing functionality is achieved, but toner fixation deteriorates and behavior in printer worsens

Engineering Contradiction:
Improveprinting functionalityVSAvoidtoner fixation, printer behavior
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes key parameters of the toner-absorbing layer: incorporating polymers with specific functional groups (carboxyl groups for toner adhesion), controlling surface properties through antistatic agents, and optimizing polymer composition ratios. These parameter changes improve toner fixation and printer behavior while maintaining basic printing functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials in the toner-absorbing layer combining thermoplastic polymers, carboxyl-containing polymers, and antistatic agents. This composite structure enhances toner fixation and overall printer behavior beyond what conventional single-material resin-coated papers can achieve.

Inventive Principle:
Principle #40Composite materials

3Productivity

If printed papers are stacked or covered immediately after printing, then storage efficiency is improved, but toner particles rub off undesirably

Engineering Contradiction:
Improvestorage efficiencyVSAvoidtoner adhesion, image integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes surface parameters of the toner-absorbing layer by incorporating antistatic agents and polymers with specific surface properties. These parameter changes increase friction and adhesion between the toner and substrate, preventing toner particles from rubbing off during stacking or covering, thus enabling efficient storage without compromising image integrity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of toner transfer during stacking into a benefit by using antistatic agents that increase surface friction. The same surface properties that could potentially cause static-related issues are instead harnessed to improve toner adhesion and prevent unwanted transfer, allowing efficient stacking and storage.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved image quality, light and ozone resistance, and better handling in printers and stackability, ensuring consistent performance and longevity of printed images.

Implementation Method 1

the polymer (C) has an average particle size d50 of 5 to 20 μm and a melting point that is above the melting range of the copolymer (A) and below the melting range of the copolymer (B)

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

The polymer combination per se can be used as a toner-absorbing layer or as a component of a toner-absorbing layer, in particular together with an antistatic agent

Methodology Applied
Scientific EffectAntistatic effect: Electrostatics

Data Source

PatentEP2326992B1Recording material for laser printing methods
Publication Date: 2015.04.22 SCHOELLER TECHNOCELL GMBH & CO KG
  • EP2326992B1 patent drawing

AI summary

Recording materials for electrophotographic methods, comprising a raw paper coated on both sides with a synthetic resin and a toner-sensitive layer, wherein the synthetic resin-coated paper has a specific surface topography, expressed as a roughness Rz of 1.5 to 13 µm, and an average Ra value of 0.05 to 2 µm, the toner-absorbing layer comprises a polymer combination of a toner-absorbing ethylene-acrylic acid copolymer (A), a carboxylated acrylic acid ester copolymer (B) and a polymer (C), and polymer (C) has an average particle size d50% of 5 to 20 µm and a melting point that is higher than the melting range of copolymer (A) and lower than the melting range of copolymer (B).