Resin Composition Compatibilization for Recycled EVOH Laminates
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Solution Overview
Problem
Existing resin compositions face compatibility issues and mechanical strength reduction when recycling laminates containing thermoplastic resins with and without polar groups and ethylene-vinyl alcohol copolymers, leading to defects like die drool, fish eyes, and reduced mechanical strength.
Innovation Solution
A resin composition combining thermoplastic resins without and with polar groups, ethylene-vinyl alcohol copolymer, acetic acid, and aliphatic carboxylic acid metal salts within specific content ranges to enhance mechanical strength and compatibility.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If collected laminates containing thermoplastic resin without polar group and EVOH are melted and reused as regrind layer, then waste reduction and economic efficiency are improved, but compatibility failure occurs causing die drool, fish eye, holes, and appearance defects
Solution Approach 1:
The patent introduces a compatibilizer as an intermediary substance to mediate between the thermoplastic resin without polar group and EVOH. The compatibilizer has both polar and non-polar characteristics, allowing it to interact with both resin types and improve their compatibility during melting and reusing processes, thereby preventing die drool, fish eye, and appearance defects while maintaining waste reduction benefits
2Reliability
If saponified EVA with high ethylene content is blended to improve compatibility, then die drool and appearance defects are reduced, but discoloration to yellow or red occurs
Solution Approach 1:
The patent changes the chemical parameters of the compatibilizer by selecting specific types with controlled saponification degrees and ethylene content. Instead of using highly saponified EVA that causes discoloration, the patent employs compatibilizers with optimized parameters that provide sufficient compatibility improvement while minimizing thermal degradation and discoloration during processing
3Object-affected harmful factors
If content of saponified EVA with high ethylene content is reduced to suppress discoloration, then discoloration is minimized, but compatibilization effect is reduced and mechanical strength decreases
Solution Approach 1:
The patent creates a composite compatibilizer system combining multiple substances with complementary functions. This includes saponified EVA with controlled parameters, thermoplastic resin with polar groups, and additional compatibility-enhancing additives. The composite approach allows each component to contribute differently to compatibilization, maintaining mechanical strength while minimizing discoloration through synergistic effects
4Reliability
If thermoplastic resin with polar group is blended to improve compatibility, then compatibility failure is reduced, but mechanical strength reduction due to compatibility failure is insufficiently improved
Solution Approach 1:
The patent applies local quality by using thermoplastic resin with polar groups specifically in the compatibilizer layer or at the interface between EVOH and non-polar thermoplastic resin layers. This localized application of polar-containing resin provides compatibility improvement exactly where needed at the interface, while the bulk layers maintain their original mechanical properties, thereby improving overall mechanical strength more effectively than uniform blending
Data Source
AI summary
A resin composition containing: a thermoplastic resin (A) that does not contain a polar group; a thermoplastic resin (B) that contains a polar group; an ethylene-vinyl alcohol copolymer (C) having an ethylene content of 20 to 60 mol %; acetic acid and/or a salt thereof (D); an aliphatic carboxylic acid (E) having 3 or more carbon atoms; and an aliphatic carboxylic acid metal salt (F) that is a metal salt of the aliphatic carboxylic acid (E), wherein the content of (A) is 66 to 99 wt. % with respect to the total sum of contents of the resin composition and the content of (C) is 0.1 to 25 wt. % with respect to the total sum of the contents of the resin composition.