Actinic-Ray-Sensitive Resin Composition for Fine Contact Hole Resolution

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Solution Overview

Problem

Current actinic-ray or radiation-sensitive resin compositions face challenges in achieving high sensitivity, resolution, and roughness performance, particularly in forming fine contact hole and isolated patterns, due to limitations in electron beam lithography such as increased backward scattering and reduced sensitivity with higher acceleration voltages.

Innovation Solution

A resin composition incorporating specific repeating units and onium salt acid generators that generate sulfonic acids of varying volumes when exposed to actinic rays or radiation, controlling acid diffusion and enhancing line edge roughness and contact hole resolution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the acceleration voltage of electron beam is increased to reduce forward scattering influence, then the resolution is improved, but the sensitivity is lowered due to reduced electron energy trapping ratio

Engineering Contradiction:
ImproveresolutionVSAvoidsensitivity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the resist film by incorporating specific compounds (compounds (1) and/or (2)) that modify the electron energy trapping characteristics. This allows the resist to maintain high sensitivity even at elevated acceleration voltages, resolving the contradiction between resolution improvement and sensitivity maintenance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite resist film system combining conventional resist materials with specific functional compounds (compounds (1) and/or (2)). This composite structure enables simultaneous optimization of both sensitivity and resolution by leveraging the complementary properties of the constituent materials.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the acceleration voltage of electron beam is increased to reduce forward scattering, then the resolution is improved, but backward scattering influence is enhanced leading to resolution deterioration in isolated patterns

Engineering Contradiction:
ImproveresolutionVSAvoidbackward scattering influence
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the resist film's chemical composition by incorporating compounds (1) and/or (2) that change the electron interaction characteristics with the resist substrate. This parameter change reduces the harmful backward scattering effects, allowing high acceleration voltage operation without resolution deterioration in isolated patterns.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potentially harmful backward scattering effect into a beneficial outcome by using the specific compound structure to control electron reflection. The modified resist composition allows controlled electron interaction that transforms the backward scattering phenomenon into an acceptable or even advantageous effect for pattern formation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of manufacture

If conventional resist compositions are used for fine contact hole and isolated patterns, then the manufacturing process is simple, but the resolution and roughness performance are insufficient

Engineering Contradiction:
Improveprocess simplicityVSAvoidresolution and roughness performance
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent employs a composite resist composition combining conventional resist materials with specific functional compounds (compounds (1) and/or (2)). This composite approach maintains ease of manufacture by using standard processing methods while achieving superior resolution and roughness performance through the synergistic effect of the combined materials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces specific functional groups and compounds (compounds (1) and/or (2)) at localized positions within the resist film structure where they can most effectively influence electron interaction and pattern formation. This local quality enhancement improves resolution and roughness performance without complicating the overall manufacturing process.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved sensitivity, resolution, and pattern shape quality for fine contact hole and isolated patterns by controlling acid diffusion and reducing development irregularities, thereby addressing the limitations of existing technologies.

Implementation Method 1

an onium salt acid generator that when exposed to actinic rays or radiation, generates a sulfonic acid

Methodology Applied
Scientific EffectPhotoacid generation: Photopolymerisation

Implementation Method 2

a resin that when acted on by an acid, is decomposed to thereby increase its alkali solubility

Methodology Applied
Scientific EffectAcid decomposition: Decomposition (biological)

Implementation Method 3

controlling acid diffusion and enhancing line edge roughness and contact hole resolution

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS9316908B2Actinic-ray- or radiation-sensitive resin composition, actinic-ray- or radiation-sensitive film, photomask blank and method of forming pattern
Publication Date: 2016.04.19 FUJIFILM CORP
  • US9316908B2 patent drawing
  • US9316908B2 patent drawing
  • US9316908B2 patent drawing

AI summary

Provided is an actinic-ray- or radiation-sensitive resin composition including (A) a resin that when acted on by an acid, is decomposed to thereby increase its alkali solubility, which resin comprises at least either any of repeating units (I) of general formula (I) below or any of repeating units (II) of general formula (II) below, (B) an onium salt acid generator that when exposed to actinic rays or radiation, generates a sulfonic acid whose volume ranges from 250 Å3 to less than 350 Å3, and (C) an onium salt acid generator that when exposed to actinic rays or radiation, generates a sulfonic acid whose volume is 400 Å3 or greater.