Resin Composition for Printed Wiring Boards

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Solution Overview

Problem

Existing resin compositions for printed wiring boards lack sufficient adhesiveness between conductor layers formed by plating and insulating layers, and do not provide adequate glass transition temperature and heat resistance after moisture absorption.

Innovation Solution

A resin composition comprising an epoxy compound, a cyanate compound, a maleimide compound, an inorganic filler, and an imidazole silane, with specific formulations and ratios, to enhance adhesiveness, glass transition temperature, and heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional resin compositions (epoxy resin, phenolic resin, imidazole silane) are used to improve adhesiveness between inner layer circuit and insulating layer, then adhesiveness is improved, but glass transition temperature remains insufficient

Engineering Contradiction:
Improveadhesiveness between inner layer circuit and insulating layerVSAvoidglass transition temperature
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The patent uses a composite resin system combining epoxy resin, phenolic resin, and imidazole silane in specific proportions. This composite material approach allows the formulation to achieve both high adhesiveness (through phenolic resin and imidazole silane) and high glass transition temperature (through epoxy resin and cyanate compound), resolving the contradiction between adhesion strength and thermal stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the compositional parameters of the resin system, specifically controlling the ratios of epoxy resin, phenolic resin, imidazole silane, and cyanate compound. By adjusting these parameters within defined ranges, the formulation achieves simultaneous improvement in adhesiveness and glass transition temperature, transforming the trade-off into a synergistic relationship.

Inventive Principle:
Principle #35Parameter changes

2Strength

If resin composition is formulated for high adhesiveness with plating metal layer, then adhesion is improved, but heat resistance after moisture absorption deteriorates

Engineering Contradiction:
Improveadhesive force between cured product and plating metal layerVSAvoidheat resistance after moisture absorption
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent employs a composite resin system including epoxy resin, phenolic resin, cyanate compound, and imidazole silane. This composite formulation provides both high adhesion to plating metal layers (through imidazole silane and phenolic resin) and excellent heat resistance after moisture absorption (through the synergistic combination of all components), eliminating the trade-off between adhesion and thermal reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The imidazole silane acts as an intermediary component that enhances the interface between the cured resin and plating metal layer, improving adhesion without compromising the bulk properties of the resin system. This intermediary function allows the formulation to achieve high adhesion while maintaining heat resistance and moisture absorption performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Quantity of substance

If laminate is thinned to improve packaging density, then packaging density is improved, but packaging reliability and warpage control deteriorate

Engineering Contradiction:
Improvepackaging densityVSAvoidpackaging reliability and warpage control
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent modifies the resin composition parameters to achieve high mechanical strength and dimensional stability even in thinned laminate configurations. By optimizing the resin system to provide superior adhesion and high glass transition temperature, the formulation enables reduced laminate thickness while maintaining packaging reliability and controlling warpage, thus resolving the contradiction between density and reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin composition achieves excellent adhesiveness between insulating and conductor layers, high glass transition temperature, and improved heat resistance after moisture absorption, thereby enhancing the performance of printed wiring boards.

Implementation Method 1

excellent adhesiveness between an insulating layer and a conductor layer formed on the surface of the insulating layer by plating

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

high glass transition temperature

Methodology Applied
Scientific EffectGlass transition: Phase Change

Implementation Method 3

excellent heat resistance after moisture absorption

Methodology Applied
Scientific EffectHeat resistance: Thermal Insulation

Data Source

PatentUS9905328B2Resin composition for printed wiring board material and prepreg, resin sheet, metal foil-clad laminate, and printed wiring board using the same
Publication Date: 2018.02.27 MITSUBISHI GAS CHEM CO INC
  • US9905328B2 patent drawing
  • US9905328B2 patent drawing
  • US9905328B2 patent drawing

AI summary

A resin composition used as a material of an insulating layer of a printed wiring board including the insulating layer and a conductor layer formed on a surface of the insulating layer by plating, the resin composition including: an epoxy compound; a cyanate compound; a maleimide compound; an inorganic filler; and an imidazole silane, wherein the maleimide compound includes a predetermined maleimide compound, a content of the maleimide compound is 25% by mass or less based on 100% by mass of a total content of the epoxy compound, the cyanate compound, and the maleimide compound, and the imidazole silane includes a compound represented by the formula (3).