Resin Laminate Dielectric Layers for Capacitance and PCB Adhesion

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Solution Overview

Problem

Existing resin compositions for capacitor dielectric layers face challenges in achieving both high capacitance and circuit adhesion, while ensuring voltage endurance and interlayer insulation reliability, as increased dielectric filler content often compromises adhesion and reliability.

Innovation Solution

A resin laminate comprising a first layer with a specific epoxy resin, diamine compound, polyimide resin, and dielectric filler, and a second layer with epoxy resin and diamine compound but without polyimide resin, optimized to enhance circuit adhesion and dielectric properties respectively, allowing for improved capacitance and reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the dielectric filler content is increased to improve capacitance, then the dielectric properties are enhanced, but the circuit adhesion and interlayer insulation reliability deteriorate

Engineering Contradiction:
Improvedielectric filler contentVSAvoidcircuit adhesion and interlayer insulation reliability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The resin composition is segmented into multiple functional components: epoxy resin for adhesion, polyimide resin for heat resistance and adhesion, diamine compound for crosslinking, and dielectric filler for capacitance. This segmentation allows each component to contribute specifically to different properties, resolving the contradiction between high filler content and adhesion reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite material system combining epoxy resin, polyimide resin, diamine compound, and dielectric filler in specific proportions. This composite approach enables the material to simultaneously achieve high capacitance (60-85 parts dielectric filler per 100 parts resin composition) and maintain excellent circuit adhesion and interlayer insulation reliability through the synergistic effects of different materials.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the polyimide resin content is increased to improve heat resistance and adhesion, then the circuit adhesion is enhanced, but the dielectric constant decreases

Engineering Contradiction:
Improvecircuit adhesionVSAvoiddielectric constant
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention optimizes the polyimide resin content within a specific range (5-30 parts per 100 parts resin composition) to balance adhesion and dielectric properties. By precisely controlling this parameter, the composition achieves both excellent circuit adhesion and high dielectric constant, resolving the contradiction between these two properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin laminate achieves enhanced circuit adhesion, voltage endurance, and interlayer insulation reliability while maintaining high capacitance, by balancing the composition and thickness of the two layers to address the trade-off between dielectric properties and adhesion.

Implementation Method 1

a resin component which comprises an epoxy resin and a diamine compound

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

a dielectric filler being a complex metal oxide comprising at least two selected from the group consisting of Ba, Ti, Sr, Pb, Zr, La, Ta, and Bi

Methodology Applied
Scientific EffectDielectric: Dielectric

Data Source

PatentUS11890853B2Resin layered product, dielectric layer, metal foil with resin, capacitor element, and printed wiring board with built-in capacitor
Publication Date: 2024.02.06 MITSUI MINING & SMELTING CO LTD
  • US11890853B2 patent drawing
  • US11890853B2 patent drawing
  • US11890853B2 patent drawing

AI summary

There is provided a resin laminate including a first layer composed of a first resin composition and a second layer composed of a second resin composition. The first resin composition includes a resin component including an epoxy resin, a diamine compound, and a polyimide resin, and a complex metal oxide including at least two selected from Ba, Ti, etc. of 60 to 85 parts by weight based on 100 parts of the first resin composition, and the content of the polyimide resin is 20 to 60 parts by weight based on 100 parts of the resin component. The second resin composition includes a resin component including an epoxy resin and a diamine compound but is free of polyimide resin, and a complex metal oxide including at least two selected from Ba, Ti, etc. of 70 to 90 parts by weight based on 100 parts of the second resin composition.