Resin Mold Composition for Imprinting Durability

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Solution Overview

Problem

The existing methods for manufacturing molds for imprinting techniques, such as photo and thermal imprinting, are costly and time-consuming, and there is a need for a resin mold with improved durability and mold release properties that can withstand repeated use without significant deterioration.

Innovation Solution

A composition comprising compounds with acryloyl or methacryloyl groups and perfluoroalkylene groups, which form a resin with high stability and cross-linking, allowing for the creation of a durable resin mold that can be cured without heat and maintains its properties during repeated use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If molds are prepared by semiconductor fine processing technologies or electric casting methods, then manufacturing precision and reliability are improved, but manufacturing cost increases and preparation time extends

Engineering Contradiction:
Improvepattern transfer precisionVSAvoidmold preparation time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The invention applies preliminary action by pre-forming a master mold with high precision patterns using conventional methods, then using this master mold to create multiple resin molds through a simplified replication process. This allows the time-consuming precision work to be done once, rather than for each individual mold needed.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention uses copying by creating resin molds that replicate the pattern from a master mold. The resin composition is cured against the master mold surface, transferring the pattern to the resin mold, which can then be used repeatedly without requiring the same complex manufacturing process each time.

Inventive Principle:
Principle #26Copying

2Productivity

If resin molds are used to reduce cost and preparation time, then manufacturing efficiency is improved, but durability and mold release properties deteriorate

Engineering Contradiction:
Improvemold preparation efficiencyVSAvoidmold durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention uses composite materials by combining a photopolymerizable compound with specific functional groups (acryloyl or methacryloyl) and a perfluoroalkylene group. The perfluoroalkylene group provides excellent mold release properties and chemical inertness, while the photopolymerizable groups enable cross-linking for durability. This composite molecular structure achieves both ease of manufacture and high reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention applies parameter changes by modifying the chemical structure of the resin composition to include perfluoroalkylene groups, which fundamentally change the surface properties and bonding characteristics of the cured resin. This chemical parameter change enables the resin mold to have both good release properties and high durability simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional resin compositions are used for mold fabrication, then ease of manufacture is maintained, but cross-linking density and resistance to swelling decrease

Engineering Contradiction:
Improveresin mold fabrication easeVSAvoidresin cross-linking stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The invention changes the chemical parameters of the resin composition by incorporating compounds with perfluoroalkylene groups and photopolymerizable groups. This enables high cross-linking density upon curing while maintaining ease of manufacture through photopolymerization. The specific molecular structure provides both manufacturing simplicity and compositional stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin mold exhibits excellent durability and mold release properties, enabling repeated formation of photocured layers with minimal swelling and surface roughness, thus supporting the efficient transfer of fine patterns in imprinting processes.

Implementation Method 1

a photopolymerizable compound (A) having a substituent (a) which is at least either one of an acryloyl group and a methacryloyl group, and a perfluoroalkylene group

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS10472446B2Composition, resin mold, photo imprinting method, method for manufacturing optical element, and method for manufacturing electronic element
Publication Date: 2019.11.12 TOYO GOSEI CO LTD
  • US10472446B2 patent drawing
  • US10472446B2 patent drawing
  • US10472446B2 patent drawing

AI summary

Described is a composition comprising: a compound (A) having a substituent (a) being at least either one of an acryloyl group and a methacryloyl group, and a perfluoroalkylene group; and a compound (B) having a substituent (b) being either one of an acryloyl group and a methacryloyl group, and a substituent (c) being either one of an acryloyl group and a methacryloyl group.