Resin Particle Mixing Temperature Control for Toner Uniformity

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Solution Overview

Problem

Existing methods for producing resin particles often result in image unevenness due to segregation of dyes within the resin particles, particularly under high-temperature high-humidity conditions.

Innovation Solution

A method involving mixing a binder resin and a dye at a temperature that satisfies the condition where the melting point of the dye is less than or equal to the temperature, which is also less than or equal to the thermal decomposition temperature of the binder resin, followed by emulsification with a basic compound, water-based solvent, and surfactant to produce resin base particle dispersion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the binder resin and dye are mixed at a temperature below the dye's melting point, then the resin maintains its structural integrity, but the dye does not melt and mix uniformly, causing image unevenness

Engineering Contradiction:
Improveuniformity of binder resin and dye mixingVSAvoidmixing temperature
Core Design Contradiction:
Manufacturing precisionVSTemperature

Solution Approach 1:

The patent applies parameter changes by precisely controlling the mixing temperature to be at or above the dye's melting point but below the resin's decomposition temperature. This temperature parameter optimization enables the dye to melt and mix uniformly with the binder resin, resolving the contradiction between maintaining resin integrity and achieving uniform dye distribution.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the mixing temperature is increased to melt the dye, then uniform mixing is achieved, but the resin may decompose if the temperature exceeds its thermal decomposition temperature

Engineering Contradiction:
Improveuniformity of binder resin and dye mixingVSAvoidresin structural integrity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent resolves this contradiction by optimizing the temperature parameter within a specific range: T1 (dye melting point) ≤ T ≤ T2 (resin decomposition temperature). This controlled parameter change ensures the dye melts for uniform mixing while the resin remains intact, preventing decomposition.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by pre-drying the mixture to reduce moisture content before heating. This preliminary step prevents premature resin decomposition and allows controlled melting of the dye, ensuring uniform mixing without exceeding the resin's thermal stability limit.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If mixing is performed without pre-drying the mixture, then the process is simpler, but moisture causes resin decomposition and dye segregation during subsequent heating

Engineering Contradiction:
Improvesimplicity of mixing processVSAvoiduniformity of binder resin and dye mixing
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by performing a pre-drying step before the main heating and mixing process. This preliminary removal of moisture prevents resin decomposition and dye segregation during subsequent heating, ensuring uniform mixing while maintaining process simplicity through a well-sequenced operation.

Inventive Principle:
Principle #10Preliminary action

4Productivity

If the dye and binder resin are mixed without precise temperature control, then the manufacturing process is faster, but image unevenness occurs due to incomplete melting or segregation

Engineering Contradiction:
Improvemixing speedVSAvoiduniformity of binder resin and dye mixing
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent resolves this contradiction by optimizing the temperature parameter to a specific range that enables rapid melting of the dye while maintaining resin stability. This controlled parameter change allows fast mixing without sacrificing uniformity, as the dye melts quickly at the optimized temperature and distributes evenly throughout the binder resin.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method produces resin particles with improved uniformity of binder resin and dye mixing, leading to images with reduced image unevenness, especially under challenging environmental conditions.

Implementation Method 1

mixing a binder resin and a dye at temperature T that satisfies formula (1) below... the melting point T1 of the dye≤the temperature T≤the thermal decomposition temperature T2 of the binder resin

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

the melting point T1 of the dye≤the temperature T≤the thermal decomposition temperature T2 of the binder resin

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Implementation Method 3

emulsifying the mixture, a basic compound, a water-based solvent, and a surfactant to thereby obtain a resin base particle dispersion

Methodology Applied
Scientific EffectEmulsification: Emulsion

Data Source

PatentUS12291609B2Method for producing resin particles and method for producing toner
Publication Date: 2025.05.06 FUJIFILM BUSINESS INNOVATION CORP
  • US12291609B2 patent drawing
  • US12291609B2 patent drawing
  • US12291609B2 patent drawing

AI summary

A method for producing resin particles includes: mixing a binder resin and a dye at temperature T that satisfies formula (1) below to thereby obtain a mixture; and emulsifying the mixture, a basic compound, a water-based solvent, and a surfactant to thereby obtain a resin base particle dispersion:the melting point T1 of the dye≤the temperature T≤the thermal decomposition temperature T2 of the binder resin.  Formula (1)