Resin Particle Surface Functionalization via Water-Soluble Mediator

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Solution Overview

Problem

Existing methods for producing resin particles fail to efficiently impart desired functions or activities to the surface of resin particles in a simple and easy manner.

Innovation Solution

A method involving the use of a thermoplastic resin with specific functional groups, such as acidic groups, is employed to create a core-shell structure with inorganic particles, where the thermoplastic resin forms the core and the inorganic particles form a shell, allowing for efficient immobilization of filler particles on the surface of resin particles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional methods are used to produce resin particles with inorganic pigment, then the production process becomes complex and difficult, but the desired function or activity cannot be efficiently imparted to the surface of resin particles

Engineering Contradiction:
Improveease of productionVSAvoidefficiency of imparting function
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

A water-soluble polymer is used as an intermediary medium to disperse both the thermoplastic resin and inorganic pigment particles uniformly. This mediator enables simple mixing and processing while ensuring efficient distribution of functional inorganic particles on the resin particle surfaces after the water-soluble polymer is removed.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the physical state and solubility parameters by using a water-soluble polymer as a temporary dispersing medium during production, then removing it to leave behind resin particles with efficiently distributed inorganic pigment. This parameter change enables simple processing while achieving high functional efficiency.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional mixing methods are used to combine inorganic pigment with resin, then the process is simple, but the inorganic pigment is not efficiently immobilized on the surface of resin particles

Engineering Contradiction:
Improvesimplicity of processVSAvoidimmobilization efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The water-soluble polymer acts as a mediator that facilitates uniform dispersion and intimate contact between the inorganic pigment particles and thermoplastic resin during the melting and mixing process. This intermediary enables reliable immobilization of pigment on particle surfaces while maintaining process simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite system during production where the water-soluble polymer, thermoplastic resin, and inorganic pigment form a temporary composite mixture that can be easily processed. After removal of the water-soluble polymer, the result is a reliable composite structure with inorganic pigment firmly attached to resin particle surfaces.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If inorganic pigment is compounded into resin material before powdering, then the structure becomes complex, but the resulting particles do not exhibit high-value-added functions effectively

Engineering Contradiction:
Improvestructural complexityVSAvoidvalue-added function
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The water-soluble polymer is extracted from the final product after serving its purpose as a dispersing medium during production. This extraction leaves behind simple resin particles with inorganic pigment efficiently distributed on their surfaces, achieving high-value-added functions without unnecessary structural complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention segments the production process into distinct stages: (1) formation of resin particles with inorganic pigment dispersed on surfaces during melting and mixing, (2) removal of water-soluble polymer, and (3) drying to obtain final particles. This segmentation achieves efficient functional distribution while maintaining structural simplicity.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the simple and efficient production of resin particles with desired properties, such as insulating, strength-enhancing, flame-resistant, electroconductive, and antimicrobial properties, suitable for various applications including cosmetics and coatings.

Implementation Method 1

the thermoplastic resin having a specific functional group satisfactorily interacts with the surface of the inorganic particles to give the core-shell structure

Methodology Applied
Scientific EffectSurface interaction: Adsorption

Implementation Method 2

the resin composition includes a matrix and resin fine particles dispersed in the matrix

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 3

removing the matrix component from the resin composition to give the resin particles

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS9233065B2Method for production of resin particle
Publication Date: 2016.01.12 DAICEL EVONIK LTD
  • US9233065B2 patent drawing
  • US9233065B2 patent drawing
  • US9233065B2 patent drawing

AI summary

Disclosed is a method for producing resin particles, which can impart a desired function to the surface of resin particles efficiently and simply. Also disclosed are resin particles produced by the method.The method produces resin particles by melting and mixing an acidic-group-containing thermoplastic resin or elastomer with filler particles and a water-soluble material to give a resin composition containing resin fine particles formed by the thermoplastic resin and the filler particles and dispersed in a matrix including the water-soluble material; and removing the matrix component from the resin composition, to give the resin particles. The resulting resin particles each include a core particle including the acidic-group-containing thermoplastic resin or elastomer, and the filler particles immobilized on the outside of the core particle. The acidic group is preferably carboxyl group or carboxylic anhydride group.