Resin Composition with Secondary Amine Monomers for Low-Temperature Curing

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Solution Overview

Problem

High-temperature curing processes in display manufacturing lead to yellowing of polymer films and substrate deformation, which are difficult to address with existing low-temperature resin compositions, especially in flexible displays.

Innovation Solution

A resin composition comprising an initiator, multifunctional monomers with secondary amine groups, a resin, a solvent, and an agent, which allows for low-temperature curing of photoresists, reducing yellowing and substrate deformation by accelerating the curing reaction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-temperature heat curing process is used for photo spacer, then curing effect is improved, but polymer film yellowing occurs which affects chroma and panel color gamut performance

Engineering Contradiction:
Improvecuring effectVSAvoidyellowing
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the curing temperature parameter from high temperature to low temperature (20-90°C) by using a specifically designed photoresist composition containing secondary amine group monomers, thereby achieving effective curing without causing yellowing of the polymer film

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite photoresist composition comprising multiple components including secondary amine group monomers, acrylic monomers, and specific initiators, which work together to enable low-temperature curing while maintaining curing effectiveness and preventing yellowing

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If material adjustment is made to improve extreme chroma performance, then chroma performance is improved, but development time increases and formulation becomes difficult

Engineering Contradiction:
Improvechroma performanceVSAvoidadjustment time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent systematically optimizes the composition parameters of the photoresist, including the types and ratios of monomers and initiators, to achieve low-temperature curing capability while maintaining good chroma performance, thereby avoiding lengthy material adjustment processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces secondary amine group monomers as intermediary compounds that facilitate low-temperature curing reactions, acting as a mediator between the initiator and acrylic monomers to enable effective curing at lower temperatures without requiring extensive material adjustments

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If low-temperature curing is implemented, then yellowing is reduced, but curing reaction rate may be insufficient

Engineering Contradiction:
ImproveyellowingVSAvoidreaction rate
Core Design Contradiction:
Object-affected harmful factorsVSSpeed

Solution Approach 1:

The patent employs a composite photoresist system combining secondary amine group monomers with acrylic monomers and specific initiators, where the synergistic interaction of components compensates for the lower reaction rate at low temperatures while preventing yellowing

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the molecular structure parameters of the monomers, particularly using secondary amine groups that enhance reactivity, and adjusts initiator selection to maintain adequate curing reaction rates at low temperatures without causing yellowing

Inventive Principle:
Principle #35Parameter changes

4Reliability

If high-temperature curing is used in flexible displays, then curing is achieved, but substrate deformation occurs

Engineering Contradiction:
ImprovecuringVSAvoidsubstrate deformation
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent changes the curing temperature parameter to low temperature (20-90°C) range, which is sufficient to achieve complete curing of the photoresist while remaining below the temperature threshold that would cause deformation of flexible display substrates

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables effective low-temperature curing of photoresists, reducing high-temperature yellowing and substrate deformation in flexible displays, thereby improving color gamut performance and process efficiency.

Implementation Method 1

The cured photoresist is formed by curing a resin composition with light at low temperature

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS10738241B2Resin composition, cured photoresist and display panel
Publication Date: 2020.08.11 TCL CHINA STAR OPTOELECTRONICS TECHNOLOGY CO LTD
  • US10738241B2 patent drawing
  • US10738241B2 patent drawing
  • US10738241B2 patent drawing

AI summary

The present disclosure provides a resin composition, a cured photoresist and a display panel. The resin composition includes an initiator, at least one multifunctional monomer, a resin, a solvent, and an agent; wherein the multifunctional monomer comprises a monomer compound with the secondary amine group. Through the above-mentioned method, the present disclosure can realize the low-temperature curing of a photoresist, and can further reduce the phenomenon of high-temperature yellowing of the organic flat layer material during the subsequent curing process, and the high-temperature deformation of the substrate can be avoided in the application of flexible displays.