Resin Processing Stabilizer Composition for Thermal Oxidation Control

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Solution Overview

Problem

Existing phenolic and phosphorus-based antioxidants are insufficient in stabilizing organic materials against heat and oxygen-induced deterioration during processing.

Innovation Solution

A combination of specific phenolic compounds, represented by Formulas (I) and (II), is used in a ratio of 0.02 to 10 parts by mass of (II) to 100 parts by mass of (I), to enhance the stability of resins and organic materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional phenolic and phosphorus-based antioxidants are used, then organic materials can be stabilized to some extent, but the stabilization effect against heat and oxygen-induced deterioration is insufficient

Engineering Contradiction:
Improvestabilization effectVSAvoidheat and oxygen-induced deterioration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite antioxidant system combining compound (I) with specific phenolic compounds (Formula II) having particular molecular structures. This composite approach creates synergistic effects where the combination provides superior stabilization against heat and oxygen compared to individual antioxidants, directly resolving the insufficiency of conventional single-antioxidant systems.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the molecular parameters of the antioxidant compounds by specifying precise structural features in Formula (II) including the R1, R2, R3, and R4 substituent patterns. These parameter changes in molecular structure enable the antioxidants to more effectively intercept free radicals and prevent oxidation, thereby enhancing the stabilization effect against thermal and oxidative deterioration.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If higher concentrations of antioxidants are added to improve stabilization effect, then processing stability improves, but the complexity of formulation and potential adverse effects increase

Engineering Contradiction:
Improveprocessing stabilityVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes the concentration parameters by establishing a specific ratio range of compound (II) to compound (I) (0.01-10 parts by mass). This parameter optimization achieves effective processing stability within a controlled compositional range, avoiding the need for excessively high antioxidant concentrations that would increase formulation complexity and potential adverse effects.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound mixture effectively reduces thermal and oxidative deterioration, inhibits viscosity increase, and prevents coloring in organic materials, particularly thermoplastic resins and engineering plastics.

Implementation Method 1

various phenolic antioxidants and phosphorus-based antioxidants have been previously developed, and it is known that organic materials can be stabilized by adding these antioxidants to the organic materials

Methodology Applied
Scientific EffectAntioxidation: Oxidation

Implementation Method 2

a compound having a superior stabilization effect is desired

Methodology Applied
Scientific EffectThermal stabilization: Heat Treatment

Data Source

PatentEP4650401A1Processing stabilizer, resin composition, and organic material stabilizing method
Publication Date: 2025.11.19 SUMITOMO CHEM CO LTD
  • EP4650401A1 patent drawing
  • EP4650401A1 patent drawing
  • EP4650401A1 patent drawing

AI summary

Provided is a process stabilizer containing a compound (I) represented by Formula (I) and a compound (II) represented by Formula (II) [wherein, R1 represents an alkyl group having 1 to 2 carbon atoms], in which the content of the compound (II) is 0.02 to 10 parts by mass with respect to 100 parts by mass of the compound (I):