Resist Composition for High-Accuracy Plated Molded Articles

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Solution Overview

Problem

Conventional resist compositions used in plating treatments lack accuracy in forming high-quality resist patterns and plated molded articles.

Innovation Solution

A resist composition comprising a compound with a quinone diazide sulfonyl group, a resin with an acid-labile group, an alkali-soluble resin, and an acid generator, which enhances the accuracy of resist patterns and plated molded articles by controlling solubility and crosslinking properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a conventional resist composition is used, then the plating treatment can be performed, but the accuracy of the resist pattern and plated molded article is insufficient

Engineering Contradiction:
Improveaccuracy of resist pattern and plated molded articleVSAvoidresistance to plating treatment
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent uses a composite resist composition containing a compound with a quinone diazide sulfonyl group, a resin with acid-labile groups, an alkali-soluble resin, and an acid generator. This composite formulation provides both high manufacturing precision through controlled solubility changes and sufficient reliability by maintaining resistance to plating treatments and developers

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent controls the solubility parameters of the resist composition by selecting specific compounds with quinone diazide sulfonyl groups and resins with acid-labile groups. The acid generator enables controlled chemical changes during exposure, transforming the resist from insoluble to soluble in specific regions, achieving high pattern accuracy while maintaining overall structural integrity during plating

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the resist pattern is made more resistant to plating treatment, then the accuracy improves, but the complexity of the resist composition increases

Engineering Contradiction:
Improveaccuracy of resist patternVSAvoidcomplexity of resist composition
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The compound with the quinone diazide sulfonyl group serves multiple functions: it acts as a light-sensitive component for pattern formation, provides structural backbone for the resist, and enables controlled solubility changes. The acid-labile groups in the resin similarly provide both pattern definition and controlled dissolution properties, reducing the need for additional specialized additives and simplifying the overall composition

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resist composition achieves high accuracy in forming resist patterns and plated molded articles by improving resistance to plating treatments and developers, leading to enhanced precision and quality.

Implementation Method 1

a compound (I) having a quinone diazide sulfonyl group, a resin comprising a structural unit having an acid-labile group (A1), an alkali-soluble resin (A2) and an acid generator (B)

Methodology Applied
Scientific EffectPhotochemical reaction: Photopolymerisation

Implementation Method 2

a resin comprising a structural unit having an acid-labile group (A1)

Methodology Applied
Scientific EffectAcid-labile group decomposition: Hydrolysis

Data Source

PatentUS11543749B2Resist composition and method for producing resist pattern, and method for producing plated molded article
Publication Date: 2023.01.03 SUMITOMO CHEM CO LTD
  • US11543749B2 patent drawing
  • US11543749B2 patent drawing
  • US11543749B2 patent drawing

AI summary

The present invention provides a resist composition which has sufficient resistant to a plating treatment and is capable of forming a resist pattern with high accuracy. The present invention also provides a method for producing a resist pattern using the resist composition, and a method for producing a plated molded article using the resist pattern. The present invention relates to a resist composition comprising a compound (I) having a quinone diazide sulfonyl group, a resin comprising a structural unit having an acid-labile group (A1), an alkali-soluble resin (A2) and an acid generator (B); a method for producing a resist pattern using the resist composition; and a method for producing a plated molded article using the resist pattern.