Resistive Memory Ion Source Adhesion

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Solution Overview

Problem

Conventional resistive memory elements face issues with delamination due to internal stresses and material interface characteristics, which can hinder fabrication and lead to performance and durability problems during processing and operation.

Innovation Solution

Incorporating an ion source material with a chalcogen, active metal, and additional elements like titanium, zirconium, or germanium to enhance interfacial adhesion strength, reduce internal stress, and improve electrical properties, along with the use of interfacial materials to facilitate adhesion between the active and ion source materials and electrodes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional ion source material is used, then the resistive memory element can be fabricated, but delamination occurs due to internal stresses and interface characteristics

Engineering Contradiction:
Improveinterfacial adhesion strengthVSAvoiddelamination
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the composition parameters of the ion source material by incorporating specific additional elements (titanium, zirconium, germanium) alongside the chalcogen and active metal. This compositional parameter change reduces internal stresses and enhances interfacial adhesion strength, preventing delamination during fabrication and operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ion source material by combining chalcogen, active metal, and additional elements (titanium, zirconium, or germanium). This composite structure leverages the synergistic properties of each component to reduce internal stresses and improve interfacial adhesion, thereby preventing delamination.

Inventive Principle:
Principle #40Composite materials

2Reliability

If ion source material with additional elements is used, then interfacial adhesion strength increases, but device complexity increases

Engineering Contradiction:
Improveinterfacial adhesion strengthVSAvoidmaterial composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent specifies precise compositional parameters for the ion source material, including the types and ratios of chalcogen, active metal, and additional elements. By controlling these parameters within defined ranges, the patent achieves improved adhesion while managing complexity through standardized material formulations.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution increases interfacial adhesion strength, reduces delamination, and enhances electrical characteristics such as switching endurance and resistance ratios, leading to improved manufacturability, performance, and durability of resistive memory elements and devices.

Implementation Method 1

The conductive filament is formed and/or set by the movement of Cu, Ag, or Zn cations (e.g., by application of a voltage across the ion source material) from the ion source material, through the active material, and to the conductive material, where the Cu, Ag, or Zn cations are electrochemically reduced and deposited

Methodology Applied
Scientific EffectElectrochemical reduction: Redox Reactions

Implementation Method 2

The conductive filament can be reset (e.g., by applying a voltage with reversed polarity across the ion source material) by ionizing and returning the Cu, Ag, or Zn atoms to the ion source material

Methodology Applied
Scientific EffectIonization: Ionisation

Data Source

PatentUS8598560B1Resistive memory elements exhibiting increased interfacial adhesion strength, methods of forming the same, and related resistive memory cells and memory devices
Publication Date: 2013.12.03 MICRON TECHNOLOGY INC
  • US8598560B1 patent drawing
  • US8598560B1 patent drawing
  • US8598560B1 patent drawing

AI summary

A resistive memory element comprising a conductive material, an active material over the conductive material, and an ion source material on the active material and comprising at least one chalcogen, at least one active metal, and at least one additional element. Additional resistive memory elements, as well as methods of forming resistive memory elements, and related resistive memory cells and resistive memory devices are also described.