Resistive Memory Layer Patterning via Interfacial Conductive Barrier

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Solution Overview

Problem

In semiconductor device manufacturing, achieving uniformity of resistive memory layers is crucial for high-quality memory devices, but existing methods face challenges in maintaining resistance characteristics and preventing non-uniform interfacial contact resistance due to direct contact between the resistive memory layer and the carbon-containing layer, leading to potential damage and operational characteristic variations in memory cells.

Innovation Solution

A method involving the sequential formation of an interfacial conductive layer, an etch stop layer, and a main conductive layer, with a carbon-containing layer acting as an etch stop and adhesive layer, is employed to pattern the resistive memory layer using an upper electrode structure as an etch mask, ensuring controlled etching and preventing ion or carbon penetration, thereby maintaining resistance uniformity and preventing damage to the resistive memory layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If the resistive memory layer is directly contacted with the carbon-containing layer, then the manufacturing process is simplified, but the resistance uniformity deteriorates and interfacial contact resistance becomes non-uniform

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidresistance uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

An interfacial conductive layer is introduced between the resistive memory layer and the carbon-containing etch stop layer. This intermediary layer prevents direct contact between the resistive memory layer and carbon, thereby maintaining resistance uniformity and preventing non-uniform interfacial contact resistance while still enabling the manufacturing process to proceed.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If the resistive memory layer is directly contacted with the carbon-containing layer, then the manufacturing process is simplified, but the reliability deteriorates due to potential damage and operational characteristic variations

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidmemory cell operational consistency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The interfacial conductive layer serves as a protective intermediary that prevents carbon from the etch stop layer from penetrating into and damaging the resistive memory layer. This ensures the reliability and operational consistency of memory cells by preventing unwanted reactions and maintaining the integrity of the resistive memory layer during the etching process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If the resistive memory layer uniformity is improved by adding protective layers, then the reliability is improved, but the device complexity increases

Engineering Contradiction:
Improveresistive memory layer uniformityVSAvoidlayer structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The barrier layer is segmented into multiple functional sub-layers: an interfacial conductive layer for protection and conductivity, and a carbon-containing etch stop layer for controlled etching. This segmentation allows each layer to perform its specific function efficiently, improving resistive memory layer uniformity while keeping the overall structure manageable through clear functional division.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS9748481B2Semiconductor device including a resistive memory layer and method of manufacturing the same including the cleaning of byproducts
Publication Date: 2017.08.29 SK HYNIX INC
  • US9748481B2 patent drawing
  • US9748481B2 patent drawing
  • US9748481B2 patent drawing

AI summary

A method of semiconductor device fabrication that includes sequentially forming an interfacial conductive layer and an etch stop layer on a resistive memory layer; forming a main conductive layer on the etch stop layer; exposing a portion of the etch stop layer by patterning the main conductive layer; exposing a portion of the interfacial conductive layer by patterning the portion of the etch stop layer; forming an upper electrode structure by patterning the portion of the interfacial conductive layer; cleaning a surface of the upper electrode structure and an exposed surface of the resistive memory layer; and patterning the resistive memory layer using the upper electrode structure as an etch mask.