Resistive Switching Device Solid Electrolyte Integration

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Solution Overview

Problem

Conventional non-volatile memory technologies face challenges in scaling due to extreme demands, requiring new materials and system architectures to achieve low energy, high speed, and high reliability, with resistive switching devices experiencing integration issues and complex operational conditions incompatible with modern low voltage logic CMOS designs.

Innovation Solution

A resistive switching device is fabricated with a specific structure involving a dielectric layer, a conductive barrier layer on the sidewalls of an opening, a fill material, a solid electrolyte layer contacting only the fill material, and a top electrode, which simplifies integration and reduces the number of added masks, allowing for scalable operational conditions and minimal impact on CMOS technology.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional non-volatile memory technologies are used, then memory storage is achieved, but integration complexity and operational voltage requirements increase

Engineering Contradiction:
Improvememory storageVSAvoidintegration complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The device is segmented into distinct functional layers: a solid electrolyte layer containing mobile ions, an inert electrode providing structural support, and an active electrode controlling ion migration. This segmentation allows each component to be optimized independently while simplifying overall integration into CMOS processes

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The solid electrolyte layer acts as an intermediary medium that enables resistive switching through ion migration. This intermediary layer facilitates the transition between high and low resistance states without requiring complex external control circuits, thereby reducing integration complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If conventional non-volatile memory technologies are used, then memory storage is achieved, but operational voltage requirements become incompatible with low voltage logic CMOS designs

Engineering Contradiction:
Improvememory storageVSAvoidoperational voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The device utilizes changes in ionic concentration within the solid electrolyte layer to modulate electrical resistance. By controlling the concentration of mobile ions through voltage-driven migration, the device achieves resistive switching at low operational voltages compatible with modern CMOS logic levels

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces conventional charge-based memory mechanisms with ion migration-based resistive switching. This substitution enables memory operation at lower voltages by utilizing the movement of ions through the solid electrolyte rather than requiring high-voltage charge storage mechanisms

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If aggressive scaling is applied to meet Moore's law demands, then device density increases, but manufacturing precision and reliability requirements become more difficult to achieve

Engineering Contradiction:
Improvedevice densityVSAvoidmanufacturing precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The solid electrolyte layer serves multiple functions simultaneously: it provides the medium for ion migration, acts as a barrier to ion diffusion into electrodes, and enables resistive switching behavior. This multi-functionality reduces the number of additional process steps required for scaling while maintaining manufacturing precision

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The device structure nests the solid electrolyte layer within existing CMOS process layers, integrating the resistive switching element into the conventional memory architecture. This nesting approach allows density improvement without requiring completely new manufacturing processes, thereby maintaining achievable precision levels

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables low operational voltage, low current consumption, and ultrafast switching, making it suitable for embedded applications and overcoming the limitations of traditional memory technologies.

Implementation Method 1

CBRAM memory devices utilize solid state electrochemistry to modulate the resistance of certain materials known as solid electrolytes by reversibly creating a nanoscale conductive link inside them when biased by small voltages

Methodology Applied
Scientific EffectIon migration: Electrophoresis

Implementation Method 2

Under the influence of an electric field the electron current from the cathode reduces an equivalent number of Ag-ions as injected from the anode and a metal-rich electrodeposit is thereby formed in the electrolyte

Methodology Applied
Scientific EffectElectrochemical reaction: Electrolysis

Implementation Method 3

a conductive barrier layer disposed on sidewalls of the opening

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS8941089B2Resistive switching devices and methods of formation thereof
Publication Date: 2015.01.27 GLOBALFOUNDRIES US INC
  • US8941089B2 patent drawing
  • US8941089B2 patent drawing
  • US8941089B2 patent drawing

AI summary

In accordance with an embodiment of the present invention, a resistive switching device includes an opening disposed within a first dielectric layer, a conductive barrier layer disposed on sidewalls of the opening, a fill material including an inert material filling the opening. A solid electrolyte layer is disposed over the opening. The solid electrolyte contacts the fill material but not the conductive barrier layer. A top electrode is disposed over the solid electrolyte.