Reusable Mold Nanostructuring for Polymer Electrodes

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Solution Overview

Problem

Existing methods for nanostructuring electrodes are difficult, time-consuming, costly, and resource-wasteful, and often require sacrificial templates, limiting their reproducibility and scalability for applications in photovoltaic cells, light-emitting diodes, and field-effect transistors.

Innovation Solution

A method involving a reusable mold with nano-concavities to create nanoarchitectured polymers, which are then transferred to a substrate and coated with electrode materials, allowing for the production of nanostructured electrodes without adhesive materials and enabling large-scale, cost-effective manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional photolithography or sacrificial template methods are used to form nanostructures, then nanostructured electrodes can be produced, but the process becomes difficult, time-consuming, costly, and resource-wasteful

Engineering Contradiction:
Improvenanostructure formationVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent uses a reusable mold with nano-concavities that serves as a master template to copy nanostructures onto polymer layers multiple times. This copying approach eliminates the need for sacrificial templates that must be discarded after single use, enabling high-volume production of nanostructured electrodes with consistent precision across large quantities.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent changes the physical state of the polymer from solid to liquid by heating above its glass transition temperature, allowing the mold to be pressed into the softened polymer to form nanostructures. This parameter change enables simple, rapid nanostructure formation without complex lithography processes, dramatically improving production efficiency while maintaining precision.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If sacrificial templates are used to form nanostructures, then nanostructured electrodes can be produced, but reproducibility is limited and scalability is reduced

Engineering Contradiction:
Improvenanostructure patternVSAvoidreproducibility
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The reusable mold serves as a universal template that can be applied to multiple polymer layers and substrates repeatedly. This multi-functional mold enables consistent reproduction of the same nanostructure pattern across different production batches and scales, eliminating the variability inherent in sacrificial template methods where each template is used only once.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The mold is prepared in advance with precise nano-concavities formed through single-shot nanolithography, establishing a master pattern that is then repeatedly copied. This preliminary creation of a durable master template ensures high reproducibility, as the same precise pattern can be transferred to numerous polymer layers without degradation or variation.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If existing nanostructuring methods are used, then nanostructured electrodes can be produced, but production costs are high and resource waste occurs

Engineering Contradiction:
Improvenanostructure formationVSAvoidmaterial waste
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

Instead of discarding sacrificial templates after single use, the patent recovers and reuses the mold hundreds or thousands of times. The reusable mold maintains its nano-concavity pattern intact through repeated pressing cycles, dramatically reducing material waste and production costs while maintaining consistent nanostructure formation precision.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The patent replaces expensive, single-use sacrificial templates with a durable, reusable mold that can be used indefinitely. This substitution eliminates the need to continuously manufacture and discard expensive templates, reducing both material consumption and production costs while maintaining high manufacturing precision through consistent pattern replication.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach facilitates the production of high-surface-area nanostructured electrodes with tunable dimensions, enhancing electron/hole transport and increasing efficiency in devices like photovoltaic cells, while reducing production costs and improving reproducibility.

Implementation Method 1

heating the mold at a sufficient temperature for a sufficient time period to produce a mold containing nanoarchitectured polymer

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 2

contacting the thin film of the polymer on the substrate with the mold containing the nanoarchitectured polymer such that the nanoarchitectured polymer contacts and adheres to the coated substrate in the absence of adhesive materials

Methodology Applied
Scientific EffectThermal adhesion: Adhesive

Implementation Method 3

depositing a first electrode material onto the nanoarchitectured polymer to form a continuous electrode coating

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS8859423B2Nanostructured electrodes and active polymer layers
Publication Date: 2014.10.14 THE ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIV OF ARIZONA
  • US8859423B2 patent drawing
  • US8859423B2 patent drawing
  • US8859423B2 patent drawing

AI summary

Embodiments of methods for fabricating polymer nanostructures and nanostructured electrodes are disclosed. Material layers are deposited onto polymer nanostructures to form nanostructured electrodes and devices including the nanostructured electrodes, such as photovoltaic cells, light-emitting diodes, and field-effect transistors. Embodiments of the disclosed methods are suitable for commercial-scale production of large-area nanostructured polymer scaffolds and large-area nanostructured electrodes.