RF Plasma Spray Deposition for Nanoparticle Hybrid Composites

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Solution Overview

Problem

Existing methods for fabricating metal/composite hybrid laminates are limited in achieving optimal mechanical properties and bonding of nanoparticles with fibers, particularly in aerospace applications, where structural and functional properties are crucial.

Innovation Solution

A radio frequency (RF) plasma spray process is used to form and deposit nanoparticles, such as boron nitride, silicon carbide, or carbon nanotubes directly onto fibrous materials, forming both mechanical and chemical bonds without a catalyst, and allowing for the adjustment of nanotube lengths and properties to meet specific application requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional compression methods are used to fabricate metal/composite hybrid laminates, then the manufacturing process is simple, but the mechanical properties and bonding of nanoparticles with fibers are insufficient

Engineering Contradiction:
Improveinter-laminar shear strengthVSAvoidfabrication process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by utilizing RF plasma spray deposition parameters (power, gas flow rates, substrate distance) to control nanoparticle formation and bonding. By adjusting these parameters, the process achieves strong mechanical bonding and chemical bonding between nanoparticles and fibers, significantly improving inter-laminar shear strength while maintaining a relatively simple fabrication process.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional mechanical compression methods with RF plasma spray deposition. This substitution uses electromagnetic fields to generate plasma, which then deposits nanoparticles onto fibers through thermal and chemical mechanisms. This results in superior bonding strength and mechanical properties compared to traditional compression methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If nanoparticles are deposited without a catalyst, then the process is cleaner and more controlled, but achieving strong mechanical and chemical bonds becomes more difficult

Engineering Contradiction:
Improvebonding strengthVSAvoidprocess control difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies self-service by utilizing the RF plasma environment itself as the bonding mechanism, eliminating the need for external catalysts. The plasma provides both thermal energy for nanoparticle formation and chemical reactivity for bonding directly to the fiber surface. This self-contained approach achieves reliable bonding strength while maintaining process control through RF power and gas flow parameters.

Inventive Principle:
Principle #25Self-service

3Adaptability or versatility

If nanotube lengths are adjusted to meet specific application requirements, then the mechanical properties are optimized, but the manufacturing precision requirements increase

Engineering Contradiction:
Improveapplication-specific property tailoringVSAvoidnanotube length control precision
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent applies dynamics by making the nanotube length controllable through dynamic adjustment of RF plasma spray parameters. By varying power levels, gas flow rates, and deposition time, the process can produce nanotubes of different lengths tailored to specific application requirements. This dynamic control enables optimization of mechanical properties while maintaining manufacturability through parameter adjustment rather than complex precision machining.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enhances the mechanical properties of fiber-metal laminates by improving inter-laminar shear strength and allowing for the production of continuous coated fabrics with tailored mechanical and physical properties, extending two-dimensional properties to three dimensions.

Implementation Method 1

A radio frequency plasma process is utilized to form a plasma plume comprising nanoparticles

Methodology Applied
Scientific EffectRF plasma: Plasma

Implementation Method 2

utilizing a radio frequency ('RF') plasma spray process to synthesize nanoparticles and to deposit the nanoparticles on a substrate

Methodology Applied
Scientific EffectPlasma spray deposition: Plasma Spray

Data Source

PatentUS9963345B2Nanoparticle hybrid composites by RF plasma spray deposition
Publication Date: 2018.05.08 UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR NAT AERONAUTICS & SPACE ADMINISTRATION
  • US9963345B2 patent drawing
  • US9963345B2 patent drawing
  • US9963345B2 patent drawing

AI summary

A method of fabricating a composite material includes utilizing a radio frequency plasma process to form a plasma plume comprising nanoparticles. The nanoparticles may comprise boron nitride nanoparticles, silicon carbide nanoparticles, beryllium oxide nanoparticles, or carbon nanoparticles. The nanoparticles may comprise nanotubes or other particles depending on the requirements of a particular application. The nanoparticles are deposited on a substrate by directing a plasma plume towards the substrate. The nanoparticles are formed in the plasma plume immediately prior to being deposited on the substrate. The nanoparticles may form a mechanical bond with the fibers in addition to a chemical bond in the absence of a catalyst. The substrate may comprise a fiber fabric that may optionally be coated with a thin layer of metal. Alternatively, the substrate may comprise a solid material such as a metal sheet or plate.