Linearized RF Plasma Ion Source for Self-Neutralized High-Energy Deposition

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Solution Overview

Problem

Conventional plasma sources for plasma-enhanced chemical vapor deposition (PECVD) lack the capability to increase ion energy without substrate biasing, making them ineffective for depositing mechanically durable and scratch-resistant coatings on large area substrates, such as glass and polymers, due to unstable operation and inadequate neutralization of ion beam space charge.

Innovation Solution

A linearized energetic plasma ion source with an inductively-coupled plasma chamber, an inductive antenna, and an extraction grid, which allows independent control of ion current density and energy through the application of RF and pulsed DC voltages, generating a self-neutralized ion beam without the need for substrate biasing or auxiliary electron sources.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional plasma sources are used for PECVD, then deposition can be performed on substrates, but ion energy cannot be increased without substrate biasing, limiting film durability

Engineering Contradiction:
Improvemechanical durability and scratch-resistance of coatingsVSAvoidneed for substrate biasing or auxiliary electron sources
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The plasma ion source is designed to self-neutralize its ion beam space charge through internal electron emission from the plasma chamber walls and components, eliminating the need for external auxiliary electron sources or substrate biasing mechanisms. The source serves its own neutralization need by designing the plasma chamber to naturally provide electrons for space charge compensation.

Inventive Principle:
Principle #25Self-service

2Strength

If substrate biasing is applied to increase ion energy, then ion energy can be increased, but the technique is impractical for large area moving substrates

Engineering Contradiction:
Improveion energy for film depositionVSAvoidapplicability to large area moving substrates
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The ion beam is segmented into multiple extraction zones along the plasma chamber length, with independent extraction grids that can be controlled separately. This allows the ion beam to be delivered in manageable segments that can effectively treat large area substrates as they move through the system, making the technique practical for industrial web or inline coaters.

Inventive Principle:
Principle #1Segmentation

3Productivity

If high ion current density is extracted, then deposition rate increases, but space charge neutralization becomes inadequate leading to unstable operation

Engineering Contradiction:
Improvedeposition rateVSAvoidoperational stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The plasma chamber walls and internal components serve as intermediary elements that emit electrons to neutralize the positive space charge of the extracted ion beam. By designing these chamber elements with appropriate material properties and geometries, they naturally provide the electron flux needed to maintain plasma stability during high current extraction, acting as built-in neutralization mediators.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the deposition of mechanically durable and scratch-resistant coatings like diamond-like carbon (DLC) on large area substrates with stable operation over extended periods, maintaining film quality and reducing maintenance needs.

Implementation Method 1

An inductive antenna is disposed in an interior of the plasma chamber body and is configured to supply a source of electromagnetic energy to an interior of the plasma chamber body. The antenna sustains a plasma discharge confined within the interior of the plasma chamber body as a function of a radio frequency (RF) voltage supplied to the antenna.

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Implementation Method 2

The bias voltage applied to the plasma chamber body supplies an electrostatic potential to charged species in the plasma discharge. A difference in potential between the extraction grid and the plasma chamber body is configured to accelerate the charged species in the plasma discharge out of the extraction grid to generate an output quasi-neutral plasma ion beam.

Methodology Applied
Scientific EffectElectrostatic acceleration: Electric Field

Implementation Method 3

Plasma is an ionized gas consisting primarily of positively charged ions and negatively charged electrons. The antenna sustains a plasma discharge confined within the interior of the plasma chamber body.

Methodology Applied
Scientific EffectPlasma ionization: Ionisation

Implementation Method 4

The bias voltage applied to the plasma chamber body includes a portion of the RF voltage supplied to the antenna combined with a pulsed DC voltage.

Methodology Applied
Scientific EffectElectromagnetic field coupling: Electromagnetic Induction

Data Source

PatentEP3711078B1Linearized energetic radio-frequency plasma ion source
Publication Date: 2023.06.07 DENTON VACUUM L L C
  • EP3711078B1 patent drawingFigure 1
  • EP3711078B1 patent drawingFigure 2
  • EP3711078B1 patent drawingFigure 3

AI summary

A plasma ion source includes a plasma chamber body having at least one inlet for introducing a feed gas to an interior of the plasma chamber body. The plasma chamber body is electrically isolated from a vacuum chamber attached to the plasma chamber body. An inductive antenna in an interior of the plasma chamber body is configured to supply a source of electromagnetic energy as a function of an RF voltage supplied thereto. The plasma ion source includes an extraction grid disposed at an end of the plasma chamber body. A voltage difference between the extraction grid and plasma chamber body accelerates charged species in a plasma discharge to generate an output quasi-neutral plasma ion beam. A bias voltage applied to the plasma chamber body includes a portion of the RF voltage supplied to the antenna combined with a pulsed DC voltage.