Rheology Modifiers for Oil-Based Mud Temperature Stability

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Solution Overview

Problem

Drilling fluids used in challenging geographic areas, such as marine environments, face difficulties in maintaining desirable rheological characteristics over a range of temperatures, leading to instability in wellbore servicing operations.

Innovation Solution

A non-aqueous wellbore servicing fluid comprising a rheology modifier, which is a reaction product of a polysulfide, a dimer acid, and a polyfunctional amine, is introduced to maintain stable rheological characteristics over varying temperature conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional drilling fluids are used in challenging geographic areas, then drilling operations can be conducted, but the rheological characteristics become unstable over a range of temperatures

Engineering Contradiction:
Improverheological stabilityVSAvoidtemperature range
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition of the drilling fluid through the use of specific rheology modifiers (polysulfide-dimer acid-polyfunctional amine reaction products) that change the fluid's rheological properties to remain stable across varying temperatures. This involves altering the molecular structure and interaction characteristics of the fluid to maintain consistent performance from 35°F to 400°F.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining multiple functional components in the drilling fluid system, including the base fluid, rheology modifiers (polysulfide-dimer acid-polyfunctional amine reaction products), and other additives. This composite approach creates a synergistic system where each component contributes specific properties that collectively maintain rheological stability across temperature ranges.

Inventive Principle:
Principle #40Composite materials

2Temperature

If drilling fluids are exposed to extreme temperatures, then deeper wellbores can be serviced, but desirable rheological characteristics are lost

Engineering Contradiction:
Improvetemperature resistanceVSAvoidrheological performance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent uses parameter changes by selecting and optimizing the chemical composition of rheology modifiers that specifically respond to temperature variations. The polysulfide-dimer acid-polyfunctional amine reaction products are designed to maintain their rheological modifying capabilities across extreme temperature ranges, allowing the fluid to preserve desirable characteristics even at 400°F.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies this principle through the use of specialized rheology modifiers that can be easily added to the drilling fluid system. These modifiers are designed to be effective throughout the drilling operation and can be replenished or adjusted as needed, providing a cost-effective solution for maintaining performance in extreme temperature conditions.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Adaptability or versatility

If the drilling fluid must maintain stable rheology across a broad temperature range, then it can be used in diverse environmental conditions, but the formulation becomes more complex

Engineering Contradiction:
Improveenvironmental adaptabilityVSAvoidfluid formulation complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies universality by designing rheology modifiers that perform multiple functions simultaneously: they modify rheology, provide temperature stability, and maintain performance across diverse environmental conditions. The polysulfide-dimer acid-polyfunctional amine reaction products serve as multi-functional additives that simplify the overall formulation by consolidating multiple required properties into a single component system.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent uses parameter changes to optimize the concentration and composition of rheology modifiers to achieve the desired balance between versatility and formulation simplicity. By carefully controlling the reaction parameters and final composition, the patent creates a formulation that is both adaptable to various environments and relatively simple to prepare and maintain.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The fluid maintains relatively stable yield point and gel strength across a broad temperature range, enhancing suspension ability and corrosion inhibition, thus improving the performance of drilling fluids in extreme conditions.

Implementation Method 1

a rheology modifier which is a reaction product of a polysulfide, a dimer acid and a polyfunctional amine

Methodology Applied
Scientific EffectRheology modification:

Implementation Method 2

the rheology modifier comprises a reaction product of a polysulfide, a dimer acid and a polyfunctional amine

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS9404029B2Rheology modifiers
Publication Date: 2016.08.02 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • US9404029B2 patent drawing
  • US9404029B2 patent drawing
  • US9404029B2 patent drawing

AI summary

A non-aqueous wellbore servicing fluid comprising a rheology modifier wherein the rheology modifier comprises a reaction product of a polysulfide, a dimer acid and a polyfunctional amine. A method of conducting an oilfield operation comprising placing an oil-based mud comprising a rheology modifier into a wellbore wherein the rheology modifier comprises a reaction product of a polysulfide, a dimer acid and a polyfunctional amine.