Non-sintered Shell-wrapped Ceramsite from River Sediment

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Solution Overview

Problem

The existing methods for preparing ceramsites from river sediment involve energy-intensive sintering processes, leading to high carbon emissions and heavy metal leaching, while also facing challenges in efficiently utilizing industrial solid wastes.

Innovation Solution

A method is developed to prepare non-sintered shell-wrapped ceramsites using river sediment and industrial solid wastes, involving dehydration, grinding, mixing with alkali activating powders, and multiple-step granulations to control particle size and porosity, followed by encapsulation with sulfoaluminate and Portland cements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If sintering method is used to prepare river sediment into ceramsites, then ceramsite strength is improved, but energy consumption increases and CO2 emissions increase

Engineering Contradiction:
Improveceramsite strengthVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent changes the preparation method from high-temperature sintering to low-temperature chemical activation, fundamentally altering the processing parameters. The alkali activation process occurs at ambient or slightly elevated temperatures, avoiding the high energy input of traditional sintering while achieving sufficient strength through chemical bonding of the activated binder matrix.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal-mechanical sintering process with a chemical activation process. Instead of using high temperature and pressure to densify the material, the invention uses alkali activation to trigger chemical reactions that form a binding matrix, substituting thermal-mechanical energy with chemical energy for strength development.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Strength

If sintering method is used to prepare river sediment into ceramsites, then ceramsite strength is improved, but CO2 emissions increase

Engineering Contradiction:
Improveceramsite strengthVSAvoidCO2 emissions
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the preparation method from high-temperature sintering to low-temperature chemical activation, fundamentally altering the processing parameters. The alkali activation process occurs at ambient or slightly elevated temperatures, avoiding the high energy input of traditional sintering while achieving sufficient strength through chemical bonding of the activated binder matrix.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal-mechanical sintering process with a chemical activation process. Instead of using high temperature and pressure to densify the material, the invention uses alkali activation to trigger chemical reactions that form a binding matrix, substituting thermal-mechanical energy with chemical energy for strength development.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If traditional granulation is used, then production efficiency is improved, but particle size distribution uniformity deteriorates

Engineering Contradiction:
Improveproduction efficiencyVSAvoidparticle size distribution uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent divides the granulation process into multiple sequential stages, each producing a specific particle size range. The first granulation produces coarse particles (3-10mm), the second produces medium particles (2-5mm), and the third produces fine particles (0.5-2mm). This segmented approach allows each stage to be optimized for its specific size range, achieving uniform distribution across the final product.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary classification of river sediment into different size fractions before granulation. This preliminary action ensures that each granulation stage starts with appropriately sized feed material, facilitating more uniform particle size distribution in the final product while maintaining production efficiency.

Inventive Principle:
Principle #10Preliminary action

4Productivity

If heavy metals are not immobilized in river sediment, then resource utilization is improved, but environmental pollution increases

Engineering Contradiction:
Improveresource utilizationVSAvoidheavy metal pollution
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful heavy metals in river sediment into a beneficial component by incorporating them into the ceramsite matrix through alkali activation. The heavy metals are immobilized within the chemically activated binder structure, transforming a pollution risk into a stable part of the construction material that can be safely utilized.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent creates a composite material system where river sediment, alkali activators, and solid waste particles are combined through chemical activation. This composite structure immobilizes heavy metals within the matrix while utilizing the alumina and silica content of the sediment as binding materials, achieving both pollution control and resource utilization.

Inventive Principle:
Principle #40Composite materials

5Use of energy by moving object

If alkali activation is used instead of sintering, then energy consumption is reduced, but ceramsite strength may deteriorate

Engineering Contradiction:
Improveenergy consumptionVSAvoidceramsite strength
Core Design Contradiction:
Use of energy by moving objectVSStrength

Solution Approach 1:

The patent creates a composite material system where river sediment, alkali activators, and solid waste particles are combined through chemical activation. This composite structure immobilizes heavy metals within the matrix while utilizing the alumina and silica content of the sediment as binding materials, achieving both pollution control and resource utilization.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality enhancement by creating a chemically activated binder matrix that provides localized strength at the particle level. The alkali activation process creates a dense, interlocked crystalline structure within the ceramsite particles that compensates for the lower processing temperature, maintaining sufficient strength for construction aggregate applications.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves immobilization of heavy metals, reduces energy consumption and carbon emissions, and enables the safe and green utilization of solid wastes, resulting in ceramsites with high numerical tube pressure and porosity.

Implementation Method 1

mixing the dry powdery residual soil with a solid waste powder and an alkali activating powder material

Methodology Applied
Scientific EffectAlkali activation: Chemical Bonding

Implementation Method 2

The river sediment contains a large quantity of Al2O3 and SiO2, which have the potential to generate hydraulic hydration products

Methodology Applied
Scientific EffectHydraulic hydration: Mineral Hydration

Implementation Method 3

mixing the second grade cold-bonded ceramsites with a sulfoaluminate cement and a Portland cement, and subjecting a resulting mixture to third granulation

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS12221379B2Method for preparing non-sintered shell-wrapped ceramsite using solid waste meanwhile immobilizing heavy metal in river sediment, and non-sintered river-sediment-based ceramsite
Publication Date: 2025.02.11 SHENZHEN UNIV
  • US12221379B2 patent drawing
  • US12221379B2 patent drawing
  • US12221379B2 patent drawing

AI summary

Disclosed are a method for preparing a non-sintered shell-wrapped ceramsite using solid waste meanwhile immobilizing a heavy metal in river sediment, and a non-sintered river-sediment-based shell-wrapped ceramsite, which relate to the technical field of building materials. The disclosure combines river sediment with a solid waste powder and an alkali activating powder material, and adopts multiple-step granulations to realize particle size control and physical pore formation, thereby obtaining a non-sintered ceramsite. A sulfoaluminate cement and a Portland cement are used to encapsulate the non-sintered ceramsite and form a shell by wrapping, thereby preparing a non-sintered river-sediment-based shell-wrapped ceramsite with internal porosity and dense shell.