Replacement Metal Gate Threshold Voltage Adjustment via Lanthanum Oxide and Titanium Nitride

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Solution Overview

Problem

Current RMG processes for 20 nm technology nodes face challenges in reliable threshold voltage adjustment due to high leakage currents and time-dependent dielectric breakdown, particularly affecting n-type field effect transistors, which complicate the integration of additional metal layers.

Innovation Solution

A simplified RMG process involving the conformal formation of a lanthanum oxide margin adjusting layer and a titanium nitride metal capping layer, followed by an n-type work function metal layer, to enhance threshold voltage margin and reduce susceptibility to time-dependent dielectric breakdown.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If Al diffusion is used to adjust threshold voltage in gate stack, then threshold voltage adjustment is achieved, but high leakage currents occur resulting in time dependent dielectric breakdown

Engineering Contradiction:
Improvethreshold voltage adjustmentVSAvoidtime dependent dielectric breakdown
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A titanium nitride intermediary layer is introduced between the aluminum gate metal and the high-k dielectric layer. This intermediary layer acts as a diffusion barrier that prevents aluminum atoms from migrating into the dielectric, thereby eliminating leakage currents and TDDB while still allowing the aluminum layer to provide threshold voltage adjustment through controlled diffusion at the titanium nitride interface.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The gate metal stack is segmented into multiple functional layers: an aluminum layer for threshold voltage adjustment, a titanium nitride intermediary layer for diffusion barrier and work function adjustment, and a capping layer for protection. This segmentation allows each layer to perform its specific function independently, resolving the conflict between Vth adjustment and reliability.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If nWF metal layers are used to adjust Vth, then threshold voltage adjustment is achieved, but device complexity increases due to additional metal layers and selective removal processes

Engineering Contradiction:
Improvethreshold voltage adjustmentVSAvoidadditional metal layers
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The titanium nitride layer performs multiple functions simultaneously: it serves as a diffusion barrier for aluminum, provides work function adjustment, acts as an adhesion layer, and functions as part of the gate electrode structure. This multi-functionality eliminates the need for separate nWF metal layers and selective removal processes, thereby reducing device complexity while maintaining Vth adjustment capability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The diffusion barrier function and work function adjustment function are merged into a single titanium nitride layer, eliminating the need for separate functional layers. This merging simplifies the overall gate stack structure and reduces the number of patterning and etch steps required.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach achieves additional threshold voltage margin and improved gate stack reliability with reduced leakage currents, simplifying the post-gate patterning process and enhancing the overall performance of n-type and p-type field effect transistors.

Implementation Method 1

conformally forming a margin adjusting layer in a first gate trench

Methodology Applied
Scientific EffectConformal deposition: Physical Vapour Deposition

Implementation Method 2

forming a metal capping layer on the margin adjusting layer

Methodology Applied
Scientific EffectConformal deposition: Physical Vapour Deposition

Implementation Method 3

annealing the Si capping layer

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS8912085B1Method and apparatus for adjusting threshold voltage in a replacement metal gate integration
Publication Date: 2014.12.16 GLOBALFOUNDRIES US INC
  • US8912085B1 patent drawing
  • US8912085B1 patent drawing
  • US8912085B1 patent drawing

AI summary

A methodology for enabling a gate stack integration process that provides additional threshold voltage margin without sacrificing gate reliability and the resulting device are disclosed. Embodiments include conformally forming a margin adjusting layer in a gate trench, forming a metal capping layer on the margin adjusting layer, and forming an n-type work function (nWF) metal layer on the metal capping layer.