Roll-to-Roll Graphene Doping for Scalable Conductivity

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Solution Overview

Problem

Current methods for producing graphene films are limited by the lack of effective synthesis, transfer, and doping techniques, restricting the quality and scalability of graphene films, which are essential for applications such as transparent electrodes.

Innovation Solution

A roll-to-roll doping method is introduced, where a graphene film is immersed in a doping solution or exposed to dopant vapor, allowing for the transfer and stacking of graphene layers, improving electrical characteristics and transparency through the use of a roll-to-roll process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional doping methods are used for graphene films, then doping can be achieved, but the process is not scalable and limits large-scale production

Engineering Contradiction:
Improvedoping throughputVSAvoiddoping process complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent employs a roll-to-roll dynamic doping process where the graphene film continuously moves through the doping chamber, exposing different sections to the dopant source sequentially. This dynamic approach enables large-scale doping by converting a static batch process into a continuous flow process, dramatically increasing productivity while maintaining manufacturing simplicity

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The doping process is made continuous through the roll-to-roll mechanism, where the graphene film is constantly fed through the doping zone without interruption. This continuous exposure to the dopant environment ensures uniform doping across the entire film while enabling scalable production, resolving the contradiction between throughput and process simplicity

Inventive Principle:
Principle #20Continuity of useful action

2Reliability

If graphene film thickness is increased to improve electrical conductivity, then sheet resistance decreases, but optical transparency is reduced

Engineering Contradiction:
Improveelectrical conductivityVSAvoidoptical transparency
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent modifies the doping parameters (dopant concentration, exposure time, temperature) to achieve optimal electrical conductivity in thinner graphene films. By precisely controlling these parameters, the film can maintain low sheet resistance while preserving high optical transparency, thus resolving the trade-off between conductivity and transparency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The doped graphene film creates a composite structure where the dopant molecules are integrated within the graphene lattice. This composite approach allows tuning of electrical properties through dopant selection and concentration while maintaining the inherent optical properties of the graphene base material, enabling simultaneous optimization of both conductivity and transparency

Inventive Principle:
Principle #40Composite materials

3Reliability

If graphene film is doped to reduce sheet resistance, then electrical properties improve, but the doping process complexity increases

Engineering Contradiction:
Improveelectrical propertiesVSAvoiddoping apparatus complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical doping equipment with a simplified vapor-phase or solution-phase doping chamber. Instead of using intricate ion implantation or chemical vapor deposition systems, the invention uses a straightforward exposure process where the graphene film passes through a dopant environment, significantly reducing apparatus complexity while achieving effective doping

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces a dopant vapor or solution as an intermediary medium to transfer dopant atoms to the graphene film. This intermediary approach simplifies the doping process by eliminating the need for direct contact between the graphene and complex doping equipment, reducing system complexity while maintaining effective dopant delivery

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the large-scale doping of graphene films, enhancing their electrical properties and transparency, making them suitable for various device applications, including electrodes, by reducing sheet resistance and maintaining high optical transparency.

Implementation Method 1

doping the graphene film by passing the graphene film through a doping solution containing a dopant or a dopant vapor

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

passing the graphene film through a dopant vapor generated by vaporizing the doping solution

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS9728605B2Roll-to-roll doping method of graphene film, and doped graphene film
Publication Date: 2017.08.08 GRAPHENE SQUARE INC
  • US9728605B2 patent drawing
  • US9728605B2 patent drawing
  • US9728605B2 patent drawing

AI summary

The present disclosure relates to roll-to-roll doping method of graphene film, and doped graphene film.