Room-Temperature Chitosan Antimicrobial Coating

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Solution Overview

Problem

Conventional antimicrobial coatings require high-temperature curing, are prone to peeling, and lack transparency, limiting their application and durability.

Innovation Solution

A coating composition comprising chitosan, chlorhexidine, silver nanoparticles, and a chitosan cross-linker, which can be cured at room temperature, providing a durable, transparent, and effective antimicrobial surface treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional antimicrobial coating compositions are used, then antimicrobial function is provided, but high-temperature curing is required which increases cost and may deteriorate coating properties

Engineering Contradiction:
Improveantimicrobial functionVSAvoidcuring temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the curing temperature parameter from high temperature (conventional) to room temperature (invention). This is achieved by using a water-based formulation with specific polymers and crosslinking agents that enable curing at lower temperatures, thereby reducing energy cost and preventing deterioration of coating properties while maintaining antimicrobial effectiveness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite formulation combining water, polymers (such as polyvinyl alcohol, carboxymethyl cellulose), crosslinking agents, and antimicrobial agents (silver nanoparticles, zinc oxide). This composite approach allows the coating to achieve proper adhesion and curing at room temperature while maintaining durability and antimicrobial function, resolving the contradiction between low curing temperature and coating reliability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional antimicrobial coatings are applied, then antimicrobial effect is achieved, but the coatings are easily peeled off after a period of usage, ultimately losing their functions

Engineering Contradiction:
Improveantimicrobial functionVSAvoidcoating durability
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent incorporates crosslinking agents (such as glutaraldehyde, borax, or calcium chloride) in the formulation that pre-establish strong bonding networks within the coating matrix before application. This preliminary structural preparation ensures that once the coating is applied and dries, it forms a durable, peeling-resistant layer that maintains its antimicrobial function over extended periods, directly addressing the durability issue.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The multi-component composite formulation including polymers, crosslinking agents, and antimicrobial particles creates a synergistic structure where the polymer matrix provides adhesion, crosslinking agents provide structural integrity and peeling resistance, and antimicrobial agents provide sustained functionality. This composite structure resolves the contradiction between coating durability and functional persistence.

Inventive Principle:
Principle #40Composite materials

3Reliability

If conventional antimicrobial coatings are used, then antimicrobial protection is provided, but the coatings lack transparency, which limits the application of coating

Engineering Contradiction:
Improveantimicrobial protectionVSAvoidtransparency
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent uses nanoscale antimicrobial particles (silver nanoparticles, zinc oxide nanoparticles) instead of larger conventional additives. At the nanoscale, these particles become optically transparent or translucent while retaining their antimicrobial properties. This local quality change at the particle level allows the coating to provide effective antimicrobial protection while maintaining visual transparency, thus resolving the contradiction between protection and appearance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the particle size parameter of antimicrobial agents to the nanoscale range (typically 1-100 nm). This parameter change fundamentally alters the optical properties of the antimicrobial additives, making them transparent or translucent to visible light while preserving their biological activity. This enables the coating to simultaneously achieve antimicrobial protection and aesthetic transparency.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating effectively kills >99.9% of microbes within minutes, inhibits microbial growth for weeks, and remains adhesive and transparent, suitable for various surfaces without the need for high-temperature curing.

Implementation Method 1

incubating a chitosan cross-linker with the chitosan solution to form a solution of crosslinked chitosan

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Implementation Method 2

An antimicrobial coating contains an antimicrobial agent that kills, inhibits or reduces the ability of bacteria to grow on the surface of the coating

Methodology Applied
Scientific EffectAntimicrobial action:

Implementation Method 3

the coating composition comprises chitosan, chlorhexidine, silver nanoparticles, chitosan cross-linker and water

Methodology Applied
Scientific EffectAntimicrobial action:

Data Source

PatentUS9957396B2Durable antimicrobial coating composition
Publication Date: 2018.05.01 HONG KONG APPLIED SCI & TECH RES INST
  • US9957396B2 patent drawing
  • US9957396B2 patent drawing
  • US9957396B2 patent drawing

AI summary

The presently claimed invention provides a coating composition for an antimicrobial coating, and a method for synthesizing the coating composition. A coating method for deposition of the antibacterial coating is also provided. The antimicrobial coating of the present invention is effective in providing antimicrobial function, easy to be manufactured, stable and durable.