Rotary Adsorbent Purification for Continuous Methane Processing

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Solution Overview

Problem

Current methane purification technologies, such as temperature swing adsorption, require complex valving and are costly due to the need for multiple vessels and cyclic processes, which increases capital and operating expenses in producing liquid natural gas (LNG) from distributed methane sources.

Innovation Solution

A rotary fluid processing system with a toroidal heat/mass transfer element that rotates within a housing, utilizing multiple manifolds for continuous fluid supply, regeneration, and rejuvenation, reducing the need for cyclic valves and enabling continuous flow purification with a simplified valveless or reduced-valve system.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If temperature swing adsorption with multiple vessels and cyclic processes is used, then methane purification is achieved, but device complexity and operating costs increase due to complex valving requirements

Engineering Contradiction:
Improvemethane purificationVSAvoidvalving complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The purification system is segmented into multiple adsorption beds arranged in series, where each bed performs a specific stage of purification. This segmentation allows continuous operation as one bed can be regenerated while others are actively purifying, eliminating the need for complex cyclic valve switching required in traditional single-vessel temperature swing adsorption systems.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system performs preliminary heating and regeneration of adsorbent beds in advance before they are needed for active purification service. By pre-regenerating adsorbent in dedicated regeneration zones while other beds are in service, the system avoids the need for complex real-time valve switching between service and regeneration modes.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If multiple vessels and cyclic processes are used for purification, then impurity removal is effective, but capital costs increase due to more components

Engineering Contradiction:
Improveimpurity removalVSAvoidcapital costs
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

Multiple adsorption beds are merged into a single integrated continuous flow reactor assembly with shared inlet/outlet manifolds and unified support structure. This merging reduces the total number of separate vessels, connections, and supporting components compared to traditional multi-vessel cyclic systems, thereby reducing capital costs while maintaining effective impurity removal through the series arrangement of beds.

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If traditional adsorption purifiers with heating and cooling steps are used, then adsorbent regeneration is achieved, but loss of time occurs during the cyclic process

Engineering Contradiction:
Improveadsorbent regenerationVSAvoidpurification cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The system maintains continuous purification action by arranging multiple adsorption beds in series with staggered regeneration cycles. While one bed is being regenerated, others continue to purify the methane stream, ensuring uninterrupted useful action. This eliminates the downtime associated with cyclic stop-start operation in traditional single-vessel systems.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

Adsorbent beds are regenerated in advance in dedicated regeneration zones before they are needed for service. By pre-heating and pre-regenerating adsorbent while other beds are actively purifying, the system minimizes idle time and maintains continuous production without waiting for regeneration to complete.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves continuous methane purification with reduced capital and operating costs by minimizing the number of valves and enabling efficient regeneration of the adsorbent, thus providing a more economical and efficient method for producing LNG from distributed methane sources.

Implementation Method 1

a toroidal heat/mass transfer element that rotates within a housing

Methodology Applied
Scientific EffectRotation:

Implementation Method 2

selective adsorption of certain impurities on different adsorbents such as activated alumina or zeolites

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

the saturated adsorbent is heated by several hundred degrees Fahrenheit, e.g., to 500° F., to substantially decrease the selective adsorptivity of the adsorbent

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

the clean adsorbent is cooled and prepared for another purification step

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS9302215B2Rotary fluid processing systems and associated methods
Publication Date: 2016.04.05 STABILIS SOLUTIONS INC
  • US9302215B2 patent drawing
  • US9302215B2 patent drawing
  • US9302215B2 patent drawing

AI summary

Rotary fluid processing systems and associated methods are disclosed. A purification system in accordance with the particular embodiment includes a rotatable adsorbent-containing heat/mass transfer element that is generally symmetric about a rotation axis, and includes multiple radial flow paths oriented transverse to the rotation axis and multiple axial flow paths oriented transverse to the radial flow paths. The axial flow paths and radial flow paths are in thermal communication with each other, and are generally isolated from fluid communication with each other at the heat transfer element. Particular embodiments can further include a housing arrangement having multiple manifolds with individual manifolds having an entry port and an exit port, and with individual manifolds having different circumferential locations relative to the rotation axis. Still further embodiments can include a seal arrangement positioned between the heat transfer element and the housing arrangement to expose the radial flow paths, but not the axial flow paths, to the entry and exit ports of one of the manifolds, and expose the axial flow paths, but not the radial flow paths, to the entry and exit ports of another of the manifolds.