Rotary Shear Injector Valve Amorphous Interlayer Coating

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Solution Overview

Problem

High-pressure valves with moving parts in chemical-processing apparatus face significant wear and reduced cycle lifetime due to substantial loads, leading to increased friction and leakage, especially in high-performance applications like HPLC pumps operating at pressures up to 10,000 psi or greater.

Innovation Solution

A valve with sliding components featuring a smooth diamond-like carbon (DLC) coating on a partially amorphous interlayer, which reduces friction and wear without the need for mechanical polishing, applied to both the rotor and stator substrates, enhancing the durability and longevity of the valve.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional coating methods are used on metallic substrates, then wear resistance is improved, but surface roughness increases requiring mechanical polishing

Engineering Contradiction:
Improvewear resistanceVSAvoidsurface smoothness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

An intermediate layer is introduced between the metallic substrate and the DLC coating. This intermediate layer serves as a mediator that enables the DLC coating to be deposited with atomic-layer smoothness without requiring mechanical polishing, thus resolving the contradiction between wear resistance and surface smoothness

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

A composite structure is created consisting of the metallic substrate, intermediate layer, and DLC coating layer. This multi-layer composite material combines the advantages of each layer: the metal substrate provides structural strength, the intermediate layer provides a smooth foundation for coating deposition, and the DLC layer provides wear resistance

Inventive Principle:
Principle #40Composite materials

2Productivity

If high pressure is applied to improve fluid delivery performance, then productivity is improved, but wear on moving parts increases reducing valve lifetime

Engineering Contradiction:
Improvefluid delivery performanceVSAvoidvalve cycle lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

Instead of using expensive polishing processes to achieve smooth surfaces, the patent uses a deposited intermediate layer that provides equivalent or superior smoothness at lower cost and without the complexity of mechanical polishing equipment

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the physical and chemical parameters of the coating process by depositing the intermediate layer through vapor deposition or similar processes, controlling thickness at the atomic level to achieve smooth surfaces without mechanical intervention

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly extends the valve's cycle lifetime by minimizing wear and friction, allowing for hundreds of thousands of reliable rotation cycles without the need for complex fabrication or polishing, thus improving the performance and reliability of high-pressure chromatography and HPLC systems.

Implementation Method 1

a substantially smooth diamond-like carbon (DLC) coating on sliding contact surfaces by forming the DLC coating on a substantially smooth interlayer formed of an at least partially amorphous material

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentEP2459913B1Rotary shear injector valve with coated stator surface
Publication Date: 2018.09.05 WATERS TECHNOLOGY CORP
  • EP2459913B1 patent drawingFigure 1~2B
  • EP2459913B1 patent drawingFigure 3A~3C
  • EP2459913B1 patent drawingFigure 4~5

AI summary

A valve includes a rotor and a stator. The rotor and the stator each have seal surfaces for contacting and sliding against one another during operation of the valve. Either or both of the rotor and the stator have a seal-surface coating formed by depositing an at least partially amorphous interlayer on a substrate and depositing a surface layer, including diamond-like carbon, on the interlayer. The surface layer requires no mechanical polishing.