Rotary Solution Spinning for Uniform Nanofiber Web Formation

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Solution Overview

Problem

Current methods for producing very fine fibers and fibrous webs are inefficient and lack a high throughput process to achieve uniformity, often resulting in agglomeration of atomized droplets into larger entities, which is not suitable for selective barrier applications like filters and medical gowns.

Innovation Solution

A high-speed rotary sprayer process using a rotating conical nozzle with a concave inner surface and forward surface discharge edge, where a spinning solution with polymers and solvents is distributed along the nozzle's concave surface to form separate fibrous streams through centrifugal force, optionally assisted by a shaping fluid and electrical field, to produce fibers with diameters less than 1,000 nm for uniform web formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If rotary sprayers are used to atomize the spinning solution, then the spinning solution can be broken into droplets, but the atomized droplets agglomerate into larger entities instead of forming fine fibers

Engineering Contradiction:
Improvefiber diameter uniformityVSAvoidthroughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent segments the spinning solution into separate fibrous streams as it travels along the concave inner surface of the rotating conical nozzle, preventing agglomeration of droplets. The segmentation occurs through the geometric configuration of the nozzle surface that divides the liquid stream into multiple fine streams that solidify into individual fibers before collection.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs a high-speed rotating conical nozzle where the rotation speed and concave surface geometry dynamically control the formation and distribution of fibrous streams. The dynamic rotation creates centrifugal forces that distribute the spinning solution uniformly along the concave surface, enabling continuous production of fine fibers with consistent diameter.

Inventive Principle:
Principle #15Dynamics

2Productivity

If a high speed rotary sprayer is used to form separate fibrous streams, then very fine fibers can be produced with high throughput, but the process requires precise control of spinning solution distribution along the nozzle surface

Engineering Contradiction:
ImprovethroughputVSAvoidnozzle geometry and operation
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent uses a conical nozzle with a concave inner surface that provides a curved pathway for the spinning solution. This curvature geometry naturally guides and distributes the liquid stream along the rotating surface, creating uniform fibrous streams without requiring complex external control mechanisms. The spherical/conical geometry simplifies the distribution process while maintaining precision.

Inventive Principle:
Principle #14Spheroidality (Curvature)

3Device complexity

If no electrical field is applied, then the process can operate simpler and at higher throughput, but fiber separation and uniformity may be insufficient

Engineering Contradiction:
Improveprocess simplicityVSAvoidfiber separation
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent introduces an electrical field as an intermediary mechanism to enhance fiber separation and uniformity when needed. The electrical field acts as a mediator that interacts with the charged or polarized fibrous streams, providing additional separation control without fundamentally changing the core mechanical spinning process. This allows the system to maintain simplicity while offering enhanced precision when required.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables the production of very fine, continuous fibers with uniform diameters ranging from 100 nm to 500 nm, facilitating high throughput and uniform fibrous web creation, suitable for selective barrier applications without the need for electrical fields, which improves fiber separation and collection efficiency.

Implementation Method 1

The centrifugal force supplied by the rotary sprayers produces enough shear to cause the paint to become atomized

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Implementation Method 2

The shaping fluid and electrical field draw the atomized paint to the target device

Methodology Applied
Scientific EffectElectrical field: Electric Field

Implementation Method 3

forming separate fibrous streams from the spinning solution while the solvent vaporizes to produce polymeric fibers

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS8747723B2Solution spun fiber process
Publication Date: 2014.06.10 DUPONT SAFETY & CONSTRUCTION INC
  • US8747723B2 patent drawing
  • US8747723B2 patent drawing
  • US8747723B2 patent drawing

AI summary

The invention relates to a process for forming fibers from a spinning solution utilizing a high speed rotary sprayer. The fibers can be collected into a uniform web for selective barrier end uses. Fibers with an average fiber diameter of less that 1,000 nm can be produced.