Rotating Barrel Electrode for Sludge Control in Metal Foil Plating

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Solution Overview

Problem

Existing electrode devices for manufacturing metal foils, such as lithium ion secondary battery collectors, face challenges in suppressing the formation and removal of sludge coats on the anode surface and maintaining a consistent inter-electrode distance, which affects the quality and efficiency of the metal foil production, especially when using nonaqueous electrolytic solutions or different metal materials.

Innovation Solution

The electrode device incorporates a barrel with through holes and partition walls that rotate on its axis, allowing metal anodes to collide and stir, maintaining a stable anode-cathode distance and efficiently removing sludge coats through controlled metal introduction and electrolysis, ensuring continuous and high-quality metal foil production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a soluble metal anode is used in electroplating process, then metal film can be formed on the cathode, but sludge coat forms on the anode surface preventing further dissolution

Engineering Contradiction:
Improvemetal film formation efficiencyVSAvoidsludge coat formation on anode
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The harmful sludge coat is extracted and removed from the anode surface by the rotating belt structure that periodically brings the anode into contact with the belt, enabling continuous operation without anode replacement

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The anode is designed to rotate dynamically on the rotating belt, allowing the anode surface to be continuously renewed by bringing fresh metal particles into contact with the cathode, preventing sludge coat accumulation

Inventive Principle:
Principle #15Dynamics

2Quantity of substance

If the anode dissolves during current application, then metal ions are supplied for plating, but the inter-electrode distance increases leading to higher power consumption

Engineering Contradiction:
Improvemetal ion supply for platingVSAvoidelectrolytic voltage and power consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by stationary object

Solution Approach 1:

The anode particles automatically replenish themselves by rotating and bringing fresh metal particles into the electroplating zone, maintaining constant inter-electrode distance without external intervention

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

Metal particles are pre-loaded onto the rotating belt in advance, so that as particles are consumed, fresh particles are already positioned to take their place, maintaining stable electrode spacing

Inventive Principle:
Principle #10Preliminary action

3Device complexity

If metal particles are simply placed in a container, then the structure is simple, but sludge coat cannot be effectively removed and inter-electrode distance varies

Engineering Contradiction:
Improveelectrode device structureVSAvoidsludge coat removal efficiency and inter-electrode distance stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The rotating belt introduces dynamic motion to the anode particles, causing them to rotate and move continuously, which prevents sludge coat accumulation and maintains stable electrode spacing through mechanical action

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The rotating belt performs multiple functions simultaneously: it holds the anode particles, rotates them to prevent sludge coat formation, maintains inter-electrode distance, and enables continuous operation, consolidating multiple functions into a single structure

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively suppresses sludge coat formation, maintains a stable inter-electrode distance, and enhances the productivity and quality of metal foils by continuously replenishing metals and removing consumed materials, resulting in improved tensile strength and reduced electrolysis voltage.

Implementation Method 1

current is applied between a soluble or insoluble metal (anode) and a peripheral surface of a drum (cathode) which are immersed in a liquid (plating liquid) to form a metal film (plating film) containing a component of the metal to be an anode on the peripheral surface of the drum to be a cathode

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

the inside of a barrel is charged with an appropriate amount of metal (metal chips, etc.) to be an anode, and mutual collisions of the metals (anode) are made by stirring the inside of the barrel

Methodology Applied
Scientific EffectMechanical stirring: Stirring

Implementation Method 3

application of an electroplating process is currently being studied

Methodology Applied
Scientific EffectElectroplating: Electroplating

Data Source

PatentEP3388557B1Apparatus for manufacturing a metal foil and metal foil manufacturing method using same
Publication Date: 2020.11.11 PROTERIAL LTD
  • EP3388557B1 patent drawingFigure 1~2(b)
  • EP3388557B1 patent drawingFigure 3~4
  • EP3388557B1 patent drawingFigure 5~6

AI summary

Provided are a novel electrode device capable of simultaneously solving a problem of sludge coat covering an anode surface, and a problem of increase in the inter-electrode distance between the anode and cathode, and a method for manufacturing a metal foil using the same. Disclosed is an electrode device, used while being immersed in an electroconductive liquid, the electrode device comprising: a barrel which has an outer wall having plural through holes and can store a metal soluble in the liquid during current application; a shaft passing through the inside of the barrel and having a peripheral surface to which current can be applied; and a metal introducing portion for introducing the metal into the barrel, wherein the barrel rotates on its axis. The barrel is preferably provided with plural partition walls each extending inward from the outer wall and having a gap with respect to the peripheral surface of the shaft, and plural chambers separated in the peripheral direction of the shaft by the plural partition walls.