Rotomolding Polyethylene Blend for Low Thickness Parts

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Solution Overview

Problem

Rotomolding processes face challenges in producing low thickness articles with complex angles, requiring materials with high flow characteristics and mechanical strength, as existing polyethylene compositions often sacrifice impact strength for increased flowability.

Innovation Solution

A polymer melt blend composition comprising a medium density linear polyethylene copolymer and a linear low density polyethylene copolymer, with specific density and melt flow index ranges, is used to achieve high impact resistance and flowability, suitable for complex rotomolded parts, particularly in low thickness articles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If polyethylene compositions are used to improve flowability for complex angular portions, then filling of angular portions is facilitated, but impact strength and environmental stress cracking resistance deteriorate

Engineering Contradiction:
ImproveflowabilityVSAvoidimpact strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent uses a composite polyethylene composition comprising multiple polyethylene components with different properties: a first polyethylene component with high melt flow index (15-50 g/10min) providing flowability, and a second polyethylene component with lower melt flow index (3-10 g/10min) providing mechanical strength. This composite approach allows simultaneous achievement of both flowability and impact strength that cannot be obtained with single-component polyethylene compositions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent carefully controls the melt flow index parameters of the polyethylene components to achieve the desired balance. The first component has a melt flow index of 15-50 g/10min while the second component has 3-10 g/10min, creating a synergistic effect where the blend achieves both good flowability (MFI > 10 g/10min) and adequate mechanical strength (ARM impact ≥ 40 J), resolving the contradiction between flowability and impact strength.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If polyethylene compositions are used to improve flowability for low thickness parts, then filling is improved, but mechanical properties and surface appearance deteriorate

Engineering Contradiction:
ImproveflowabilityVSAvoidsurface appearance
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The composite composition combines a high flowability component (MFI 15-50 g/10min) with a mechanically robust component (MFI 3-10 g/10min), enabling the material to flow into low thickness sections effectively while maintaining surface integrity and appearance quality, thus resolving the contradiction between flowability and surface appearance in low thickness part production.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If single polyethylene composition is used to achieve high flowability, then processability is improved, but mechanical strength properties deteriorate

Engineering Contradiction:
ImproveprocessabilityVSAvoidmechanical strength
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs a two-component polyethylene system where the first component (MFI 15-50 g/10min) provides excellent processability and flowability, while the second component (MFI 3-10 g/10min) provides mechanical strength and reliability. The specific weight ratio range (5-50 parts by weight of first component to 1-5 parts by weight of second component) ensures both processability and mechanical strength are achieved simultaneously, resolving the contradiction between processability and mechanical strength.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The blend composition enhances impact resistance, environmental stress cracking resistance, and surface finishing properties, enabling the production of low thickness articles with improved mechanical properties and flowability, suitable for various applications including automotive, agricultural, and playground parts.

Implementation Method 1

a thermoplastic material, generally in a powder form, is placed into a mold cavity... The mold is then closed, heated, and rotated vertically and horizontally, which results in the thermoplastic softening and forming to the wall of the mold

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS11746220B2High flow rotomolding compositions, processes thereof, and articles therefrom
Publication Date: 2023.09.05 BRASKEM SA
  • US11746220B2 patent drawing
  • US11746220B2 patent drawing
  • US11746220B2 patent drawing

AI summary

Compositions may include a polymer melt blend composition prepared from two polyethylene copolymers having different densities, wherein the polymer melt blend composition possesses improved flowability and impact resistance for low thickness rotomolding applications. Low thickness articles may include a polymer melt blend composition prepared from two polyethylene copolymers having different densities, wherein the articles possess improved finishing properties. Rotomolding processes may include melt blending from two polyethylene copolymers having different densities, pulverizing the melt blend, and rotational molding the composition thereof.