Resistive RAM Cell Copper Oxide Layer Resistance Distribution

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Solution Overview

Problem

Resistive RAM devices face challenges in achieving tight resistance distribution and data retention, which are crucial for multilevel storage and increased data density.

Innovation Solution

A resistive RAM cell is formed with a copper oxide layer grown directly on a copper layer, and a sidewall spacer is used to prevent copper and oxygen diffusion, improving resistance uniformity and reducing edge effects, thereby enhancing data retention and resistance distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional resistive RAM device structures are used, then device functionality is achieved, but resistance distribution is loose and data retention is poor

Engineering Contradiction:
Improveresistance distributionVSAvoiddata retention
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies local quality by creating a non-uniform oxygen concentration profile within the copper oxide layer. The oxygen concentration varies through the thickness of the layer, with different regions having different oxygen content. This gradient structure creates localized variations in resistance characteristics that improve both resistance distribution and data retention, resolving the contradiction between manufacturing precision and reliability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the oxygen concentration parameter within the copper oxide layer to optimize device performance. By controlling the oxygen partial pressure during formation and adjusting the oxygen concentration gradient, the patent achieves tighter resistance distribution and improved data retention. This parameter change approach directly addresses the technical contradiction by finding optimal oxygen concentration values that simultaneously improve both resistance uniformity and data retention.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If copper oxide layer is formed without controlled oxygen concentration, then formation process is simple, but edge effects increase and resistance uniformity decreases

Engineering Contradiction:
Improveresistance uniformityVSAvoidoxygen concentration control
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent controls the oxygen concentration parameter during the copper oxide layer formation process by adjusting oxygen partial pressure. This parameter control prevents excessive oxygen diffusion into the copper layer while avoiding oxygen depletion at interfaces. The result is improved resistance uniformity across the device without requiring overly complex formation processes, effectively balancing manufacturing precision and device complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary anti-action by controlling oxygen diffusion during the formation process to prevent harmful edge effects before they occur. By managing oxygen partial pressure and concentration during formation, the patent preemptively prevents oxygen depletion at interfaces and excessive oxygen incorporation, which would otherwise lead to poor resistance uniformity. This preliminary control resolves the contradiction by preventing defects before they affect device performance.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a tighter resistance distribution and improved data retention for resistive RAM devices, allowing for increased data density and better performance.

Implementation Method 1

a copper oxide layer grown directly on a copper layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a sidewall spacer is used to prevent copper and oxygen diffusion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS8921155B2Resistive random access memory (RAM) cell and method for forming
Publication Date: 2014.12.30 NXP USA INC
  • US8921155B2 patent drawing
  • US8921155B2 patent drawing
  • US8921155B2 patent drawing

AI summary

A resistive random access memory cell uses a substrate and includes a gate stack over the substrate. The gate stack includes a first copper layer over the substrate, a copper oxide layer over the first copper layer, and a second copper layer over the copper oxide layer.