RRAM Electrode Surface Flatness via RF PVD and Planarization

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Solution Overview

Problem

Existing methods for manufacturing electrodes for resistive random access memory (RRAM) result in rough surfaces and reduced thickness due to pinholes and high oxygen content, leading to poor electrical performance, and the requirement for a flat surface is not adequately met by conventional physical vapor deposition (PVD) processes.

Innovation Solution

A method involving the formation of a conductive layer and a radio frequency physical vapor deposition (RF PVD) transition metal compound layer, with a sacrificial layer of titanium nitride or tantalum nitride, followed by a planarization process to achieve a flat and compact RF PVD transition metal compound layer with sufficient thickness, ensuring improved electrical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If general physical vapor deposition (PVD) is used to form the electrode, then the manufacturing process is simple, but the electrode surface becomes rough with pinholes and high oxygen content, reducing electrical performance

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidelectrode surface flatness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The electrode structure is segmented into multiple layers: a lower electrode layer formed by PVD and an upper electrode layer formed by RF PVD. This segmentation allows each layer to serve different functions - the lower layer provides bulk conductivity while the upper layer provides a flat, low-oxygen surface, thus resolving the contradiction between manufacturing simplicity and surface precision

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The electrode is constructed as a composite structure combining materials deposited by different methods (PVD and RF PVD). The composite structure leverages the advantages of both deposition techniques - the simplicity of PVD for bulk formation and the superior surface quality of RF PVD for the top layer, thereby achieving both ease of manufacture and high surface precision

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If chemical mechanical polishing is used to improve the surface flatness of the lower electrode, then the surface flatness is improved, but the thickness of the lower electrode is reduced, affecting electrical performance

Engineering Contradiction:
Improvesurface flatnessVSAvoidelectrical performance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

Instead of polishing the lower electrode after formation, the invention performs preliminary action by forming an upper electrode layer with inherently flat surface through RF PVD. This preliminary action provides the required surface flatness before any subsequent processing, eliminating the need for polishing that would reduce thickness and compromise electrical performance

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The upper electrode layer acts as a copy or replica of the desired flat surface morphology. By forming this upper layer through RF PVD which naturally produces flat surfaces, the invention copies the ideal surface geometry onto the electrode structure without materially removing or thinning the lower electrode layer, thus preserving electrical performance

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a lower electrode with a flat and compact surface and sufficient thickness, enhancing the electrical performance of RRAM devices by reducing pinholes and oxygen content, thereby improving the overall performance of the memory device.

Implementation Method 1

An RF PVD transition metal compound layer is formed on the conductive layer by using a RF PVD

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 2

a planarization process is performed to remove the sacrificial layer and a portion of the RF PVD transition metal compound layer underlying the sacrificial layer

Methodology Applied
Scientific EffectChemical mechanical polishing:

Data Source

PatentUS10636967B2Method for manufacturing electrode and resistive random access memory
Publication Date: 2020.04.28 WINBOND ELECTRONICS CORP
  • US10636967B2 patent drawing
  • US10636967B2 patent drawing

AI summary

A method for manufacturing an electrode including the following steps is provided. A conductive layer is formed on a base material. A radio frequency physical vapor deposition (RF PVD) transition metal compound layer is formed on the conductive layer by using a RF PVD. A sacrificial layer is formed on the RF PVD transition metal compound layer. A planarization process is performed to remove the sacrificial layer and a portion of the RF PVD transition metal compound layer.