RRAM Metal Oxide Nanorods for Stable Operation

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Solution Overview

Problem

Conventional RRAMs face challenges with unstable operation voltage and resistance states, leading to errors in operation, especially when used in 3D high-density crossbar structures, due to the difficulty in controlling P-type and N-type oxide compositions and high-temperature processing requirements.

Innovation Solution

A resistive random access memory (RRAM) design featuring a first metal oxide composite layer with a film layer and nanorod structure, where the film layer and nanorod structure are formed using room-temperature processes such as sputtering and chemical bath deposition or hydrothermal methods, respectively, providing stable operation voltage and resistance states, and utilizing materials like ZnO, NiO, or TiO2, with electrodes made from metals like Pt or their combinations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a general PN junction diode is used as a selective element for RRAM, then the rectification property is achieved, but the composition control of oxide layers becomes difficult and operation voltage stability deteriorates

Engineering Contradiction:
Improveoperation voltage stabilityVSAvoidoxide layer composition control
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent extracts and eliminates the complex P-N junction structure, replacing it with a simplified single-layer metal oxide composite structure that maintains rectification functionality while removing the composition control difficulties associated with multiple oxide layers

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs a metal oxide composite layer combining crystalline and amorphous phases, utilizing the complementary properties of each phase to achieve both stable operation voltage and ease of manufacture without requiring precise control of multiple oxide compositions

Inventive Principle:
Principle #40Composite materials

2Reliability

If high-temperature processes are used to form oxide layers, then the rectification property is achieved, but the manufacturing cost and process complexity increase

Engineering Contradiction:
Improverectification propertyVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the temperature parameter from high-temperature to low-temperature or room-temperature processing, achieving the same rectification property through modified processing conditions that simplify manufacturing and reduce costs

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces thermal processing mechanisms with alternative deposition or formation mechanisms that operate at lower temperatures, substituting the need for high-temperature equipment and processes with simpler, more cost-effective methods

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Quantity of substance

If the RRAM is applied to 3D high-density crossbar structure, then the storage density is improved, but interference between elements occurs leading to operation errors

Engineering Contradiction:
Improvestorage densityVSAvoidoperation accuracy
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies local quality by creating distinct crystalline and amorphous regions within the metal oxide composite layer, where each region provides specific functional properties that collectively enable high-density storage with minimal interference between adjacent elements

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The RRAM achieves stable operation voltage and resistance states, reducing power consumption and manufacturing costs, while enabling efficient unipolar and bipolar operations with improved rectification properties and endurance, suitable for 3D high-density crossbar memory cell arrays.

Implementation Method 1

the film layer and the nanorod structure are formed using room-temperature processes such as sputtering and chemical bath deposition or hydrothermal methods, respectively

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 2

the film layer and the nanorod structure are formed using room-temperature processes such as sputtering and chemical bath deposition or hydrothermal methods, respectively

Methodology Applied
Scientific EffectChemical bath deposition: Chemical Vapour Deposition

Data Source

PatentUS9159918B2Resistive random access memory
Publication Date: 2015.10.13 NATIONAL TSING HUA UNIVERSITY
  • US9159918B2 patent drawing
  • US9159918B2 patent drawing
  • US9159918B2 patent drawing

AI summary

A resistive random access memory includes a first electrode, a second electrode and a first metal oxide composite layer. The second electrode is opposite to the first electrode. The first metal oxide composite layer is disposed between the first electrode and the second electrode. The first metal oxide composite layer has a film layer and a nanorod structure.