R-T-B Sintered Magnet Grain Boundary Diffusion for Coercivity
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Sintered R-T-B based magnets face a challenge in maintaining high coercivity (HcJ) at high temperatures due to irreversible thermal demagnetization, and existing methods to improve HcJ often compromise remanence (B_r) or rely on scarce heavy rare-earth elements.
Innovation Solution
A method involving a sintered R1-T-B based magnet work with specific composition and a diffusion process using an R2-Ga alloy at controlled temperatures to introduce Tb and Dy into the magnet, promoting grain boundary diffusion of light rare-earth elements and gallium, thereby enhancing coercivity without significantly reducing remanence.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If heavy rare-earth elements (Dy, Tb) are used to replace light rare-earth elements (Nd, Pr) in the R2T14B compound phase, then coercivity HcJ is improved, but remanence Br decreases due to reduced saturation magnetization
Solution Approach 1:
The patent applies local quality by concentrating heavy rare-earth elements (Dy, Tb) specifically at the grain boundaries of the R2T14B main phase through controlled diffusion, rather than uniformly distributing them throughout the entire magnet. This localized placement at grain boundaries provides the necessary coercivity enhancement while minimizing the overall heavy rare-earth content and preserving the bulk saturation magnetization, thus maintaining high remanence Br.
Solution Approach 2:
The patent employs parameter changes by precisely controlling the diffusion process parameters including temperature (700-950°C), time (0.5-4 hours), and heavy rare-earth element concentration (0.05-0.40 mass%) to achieve optimal coercivity enhancement. By adjusting these parameters, the patent optimizes the distribution and concentration of heavy rare-earth elements at grain boundaries, resolving the contradiction between improving HcJ and maintaining Br.
2Reliability
If heavy rare-earth elements such as Dy are diffused from the surface into the interior of the sintered magnet, then HcJ is improved with suppressed decrease in Br, but the use of scarce heavy rare-earth resources increases
Solution Approach 1:
The patent minimizes heavy rare-earth element consumption by applying local quality - concentrating Dy or Tb exclusively at the grain boundaries through controlled diffusion rather than uniform distribution. This localized approach achieves maximum coercivity enhancement per unit of heavy rare-earth element used, as the grain boundary phase is where these elements most effectively influence magnetic domain wall pinning.
Solution Approach 2:
The patent applies partial action by introducing only the minimum necessary amount of heavy rare-earth elements (0.05-0.40 mass%) required to achieve the desired coercivity enhancement. Rather than saturating the entire magnet with heavy rare-earth elements, the diffusion process introduces just enough at the grain boundaries to achieve the technical effect, thereby reducing overall resource consumption.
3Stability of the object's composition
If the content of heavy rare-earth elements is increased to improve HcJ, then temperature stability is improved, but resource availability and cost stability deteriorate
Solution Approach 1:
The patent applies parameter changes by optimizing the heavy rare-earth element content to a specific range (0.05-0.40 mass%) that achieves sufficient temperature stability of coercivity without excessive resource consumption. This parameter optimization balances performance requirements with resource availability and cost considerations, making the magnet commercially viable while maintaining high-temperature performance.
Solution Approach 2:
The patent resolves the contradiction between temperature stability and resource availability by applying local quality - placing heavy rare-earth elements only where they are most effective (at grain boundaries) rather than throughout the bulk material. This localized strategy achieves the necessary temperature stability with minimal heavy rare-earth content, thereby maintaining adaptability to resource constraints and cost considerations.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This approach achieves high remanence and coercivity in sintered R-T-B based magnets while minimizing the use of heavy rare-earth elements, effectively addressing the temperature stability issue and resource constraints.
Implementation Method 1
a diffusion step of, while keeping at least a portion of the R2-Ga alloy in contact with at least a portion of a surface of the sintered R1-T-B based magnet work, performing a first heat treatment at a temperature which is not lower than 700°C and not higher than 950°C in a vacuum or an inert gas ambient, to increase a content of at least one of Tb and Dy in the sintered R1-T-B based magnet work
Data Source
Figure 1~2A
Figure 2B
AI summary
A sintered R1-T-B based magnet work and an R2-Ga alloy are provided. The sintered magnet work contains R: 27.5 to 35.0 mass%, B: 0.80 to 0.99 mass%, Ga: 0 to 0.8 mass%, M: 0 to 2 mass% (where M is at least one of Cu, Al, Nb and Zr), and T: 60 mass% or more. A diffusion step of, while keeping at least a portion of the R2-Ga alloy in contact with at least a portion of a surface of the sintered magnet work, performing a first heat treatment at a temperature which is not lower than 700°C and not higher than 950°C to increase the RH amount contained in the sintered magnet work by not less than 0.05 mass% and not more than 0.40 mass%, is performed; and a second heat treatment is performed at a temperature which is not lower than 450°C and not higher than 750°C but which is lower than the temperature of the first heat treatment.