Rubber Composition Air Permeation Flexure Failure Resistance

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Solution Overview

Problem

Existing rubber compositions for inner tire liners excel in air permeation resistance but often compromise on flexure failure resistance and low-temperature characteristics, particularly in cold environments, and fail to meet weight-saving requirements.

Innovation Solution

A rubber composition comprising 100 parts by mass of rubber ingredient, 1 to 9 parts by mass of carbon black, and 80 to 150 parts by mass of layered or platy clay mineral, with the rubber ingredient being predominantly butyl-based rubber, and the carbon black and clay mineral characterized by specific iodine adsorption and aspect ratios, respectively, to enhance air permeation and flexure failure resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If soft carbon black is highly filled in rubber composition to improve air permeation resistance, then air permeation resistance is improved, but flexure failure resistance deteriorates

Engineering Contradiction:
Improveair permeation resistanceVSAvoidflexure failure resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses a composite filler system combining layered clay mineral (providing barrier effect for air permeation resistance) with soft carbon black (providing reinforcement for flexure failure resistance). This composite approach allows both properties to be optimized simultaneously rather than relying on a single filler type.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies precise parameter ranges: carbon black at 1-9 parts by mass per 100 parts rubber, clay mineral at 80-150 parts by mass per 100 parts rubber, and aspect ratio of clay mineral at 2-200. These parameter optimizations ensure the balance between air permeation resistance and flexure failure resistance.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If soft carbon black is highly filled in rubber composition to improve air permeation resistance, then air permeation resistance is improved, but low-temperature characteristics deteriorate

Engineering Contradiction:
Improveair permeation resistanceVSAvoidlow-temperature characteristics
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The layered clay mineral structure provides a physical barrier that maintains effectiveness at low temperatures, complementing the carbon black's reinforcement properties. This composite system ensures both air permeation resistance and low-temperature characteristics are maintained.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the ratio of clay mineral to carbon black (80-150 parts clay to 1-9 parts carbon black per 100 parts rubber) to ensure sufficient low-temperature flexibility while maintaining air permeation resistance. The aspect ratio control of clay mineral (2-200) also contributes to maintaining low-temperature properties.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If clay mineral is incorporated to enhance air permeation resistance, then air permeation resistance is improved, but flexure failure resistance may worsen

Engineering Contradiction:
Improveair permeation resistanceVSAvoidflexure failure resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent combines clay mineral with soft carbon black in specific proportions to create a synergistic effect. The clay mineral provides the barrier structure for air permeation resistance, while the soft carbon black network provides reinforcement for flexure failure resistance, preventing the deterioration that would occur with clay mineral alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies that soft carbon black should have iodine adsorption of at most 50 mg/g and dibutyl phthalate absorption of at most 125 ml/100 g, ensuring appropriate softness and reinforcement properties. The carbon black content (1-9 parts per 100 parts rubber) is optimized to provide sufficient flexure failure resistance while maintaining air permeation resistance through the clay mineral barrier.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved air permeation resistance and flexure failure resistance, enabling weight-saving tires with enhanced low-temperature performance and reduced air permeability, making it suitable for various vehicle types.

Implementation Method 1

the layered or platy clay mineral (C) can be aligned regularly and nearly in parallel to the extrusion direction of the composition

Methodology Applied
Scientific EffectAlignment:

Data Source

PatentUS9328213B2Rubber composition for pneumatic tire
Publication Date: 2016.05.03 BRIDGESTONE CORP
  • US9328213B2 patent drawing

AI summary

A rubber composition excellent in air permeation resistance and improved in flexure failure resistance, and a weight-saving pneumatic tire excellent in air permeation resistance and improved in flexure failure resistance in which the rubber composition is used as the inner liner therein is provided. The rubber composition contains, relative to 100 parts by mass of the rubber ingredient (A) therein, from 1 to 9 parts by mass of carbon black (B) and from 80 to 150 parts by mass of a layered or platy clay mineral (C).