Rubber Composition for Tire Tread Balancing Fuel Efficiency and Processability
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Solution Overview
Problem
Current rubber compositions that aim to improve fuel efficiency, abrasion resistance, and wet grip performance in tire treads often compromise on processability due to increased hardness from functional groups and high molecular weight polymers.
Innovation Solution
A rubber composition comprising a copolymer synthesized by copolymerization of a conjugated diene monomer and an unsaturated acyclic monoester, combined with carbon black and/or silica, which balances fuel efficiency, abrasion resistance, and wet grip performance while maintaining good processability through controlled molecular weight and molecular distribution.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Use of energy by moving object
If a functional group having an affinity for filler is introduced into the polymer end, then fuel efficiency is improved, but hardness increases and processability deteriorates
Solution Approach 1:
The patent changes the chemical structure parameters of the polymer by introducing specific functional groups (mercapto group and filler affinity group) at the polymer end through controlled copolymerization. This allows the polymer to achieve both improved fuel efficiency through filler interaction and maintained processability by controlling the timing and extent of functional group introduction during polymerization, rather than adding hardening agents that would increase overall hardness.
2Strength
If a high molecular weight polymer is used, then abrasion resistance is improved, but hardness increases and processability deteriorates
Solution Approach 1:
The patent controls the molecular weight parameter by using a chain transfer agent during copolymerization to achieve a specific weight average molecular weight range (5,000 to 2,000,000). This controlled molecular weight, combined with the functional groups at the polymer end, provides sufficient abrasion resistance while preventing excessive hardness that would compromise processability.
3Reliability
If a polymer having a high glass transition temperature is used, then wet grip performance is improved, but hardness increases and processability deteriorates
Solution Approach 1:
The patent adjusts the glass transition temperature parameter by controlling the composition ratio of conjugated diene monomer (5-95 mass%) and unsaturated acyclic monoester (5-95 mass%), and by selecting appropriate monomers with different Tg values. This allows optimization of wet grip performance through higher Tg while maintaining processability through controlled composition and molecular weight.
4Reliability
If styrene content is increased, then wet grip performance is improved, but hardness increases and processability deteriorates
Solution Approach 1:
The patent controls the styrene content parameter within a specific range (1-50 mass% of the copolymer) to achieve adequate wet grip performance. By combining controlled styrene content with controlled molecular weight and functional groups at the polymer end, the patent maintains processability while still achieving the desired wet grip performance through optimized composition parameters.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The rubber composition achieves balanced improvements in fuel efficiency, abrasion resistance, and wet grip performance while ensuring good processability, making it suitable for tire tread applications.
Implementation Method 1
a copolymer synthesized by copolymerization of a conjugated diene monomer and an unsaturated acyclic monoester
Implementation Method 2
the copolymer is synthesized by emulsion polymerization
Data Source
AI summary
Provided are a rubber composition having a good balance of improved fuel efficiency, abrasion resistance, and wet grip performance while providing good processability, and a pneumatic tire having a tread manufactured from the rubber composition. A rubber composition comprising: a copolymer synthesized by copolymerization of a conjugated diene monomer and an unsaturated acyclic monoester represented by the formula (1) below; and carbon black and/or silica, wherein R1 represents hydrogen or a C1-C30 hydrocarbon group, and R2 represents hydrogen or a C1-C30 hydrocarbon group.


