Sulphur-Linkable Rubber Mixture for Tyre Traction

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Solution Overview

Problem

Existing sulfur-crosslinkable rubber mixtures for vehicle tires do not adequately balance traction on snow, abrasion resistance, and other properties such as rolling resistance and braking behavior, often compromising one or more of these factors.

Innovation Solution

A sulfur-crosslinkable rubber mixture containing 25 to 300 phr of a hydrocarbon resin with specific molecular weight and softening point properties, combined with 50 to 100 phr of solution-polymerized diene rubber, optimized to improve traction on snow and abrasion resistance while maintaining or improving other properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional hydrocarbon resins are used in rubber mixtures, then processing aids and green stickiness are improved, but traction on snow and abrasion resistance are insufficient

Engineering Contradiction:
Improvegreen stickinessVSAvoidtraction on snow
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies parameter changes by selecting hydrocarbon resins with specific molecular weight ranges (Mz: 2,500 to 10,000 g/mol) and softening point ranges (60°C to 120°C), along with controlled Q values (0.020 to 0.040 °C·g/mol). These precise parameter specifications optimize both the processing characteristics (green stickiness) and winter performance (traction on snow) of the rubber mixture, resolving the contradiction between ease of operation and reliability in snowy conditions.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If hydrocarbon resins are added to rubber mixtures, then green stickiness is improved, but abrasion resistance deteriorates

Engineering Contradiction:
Improvegreen stickinessVSAvoidabrasion resistance
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent resolves this contradiction through parameter changes by specifying narrow ranges for molecular weight (Mz: 2,500 to 10,000 g/mol) and softening point (60°C to 120°C) of the hydrocarbon resin. These controlled parameters ensure that the resin provides adequate green stickiness for processing while simultaneously maintaining or improving abrasion resistance, preventing the deterioration that occurs with conventional resins.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If existing rubber mixtures are formulated, then processing is feasible, but a balance between traction on snow, abrasion resistance, rolling resistance, and braking behavior cannot be achieved

Engineering Contradiction:
Improveprocessing feasibilityVSAvoidbalanced performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies parameter changes by defining specific ranges for hydrocarbon resin content (25 to 300 phr), molecular weight (Mz: 2,500 to 10,000 g/mol), softening point (60°C to 120°C), and Q value (0.020 to 0.040 °C·g/mol). These coordinated parameter specifications enable simultaneous optimization of processing feasibility and balanced performance across multiple critical properties including traction on snow, abrasion resistance, rolling resistance, and braking behavior.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by formulating a multi-component rubber mixture system that combines diene rubber (50 to 100 phr) with hydrocarbon resin (25 to 300 phr) and various additives. This composite approach allows the synergistic interaction between components to achieve balanced performance across multiple contradictory requirements, including winter traction, abrasion resistance, and processing characteristics.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The rubber mixture achieves enhanced traction on snow and increased abrasion resistance without compromising rolling resistance or braking performance, and maintains or improves other indicators like tensile strength and stiffness.

Implementation Method 1

They serve primarily as processing aids and give the rubber mixtures the necessary green stickiness. Furthermore, certain vulcanizate properties such as hardness, modulus and swelling behavior can be influenced by resins. They can also be used as vulcanization resins or adhesion promoters.

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

The invention relates to a sulfur-crosslinkable rubber mixture and a vehicle tire. The rubber mixture contains 50 to 100 phr of at least one solution-polymerized diene rubber and 25 to 300 phr of a hydrocarbon resin

Methodology Applied
Scientific EffectSulfur crosslinking: Chemical Bonding

Data Source

PatentEP3006226B1Sulphur linkable natural rubber mixture and vehicle tyre
Publication Date: 2018.12.26 CONTINENTAL REIFEN DEUTSCHLAND GMBH
  • EP3006226B1 patent drawing
  • EP3006226B1 patent drawing
  • EP3006226B1 patent drawing

AI summary

The invention relates to a sulfur-curable rubber compound and a vehicle tire incorporating the sulfur-curable rubber compound in at least one component. The sulfur-curable rubber compound exhibits optimized traction properties on snow and increased abrasion resistance with the same or improved other properties. For this purpose, the rubber compound comprises at least the following components: - At least one hydrocarbon resin, which consists of 50 to 100 wt.% aliphatic C5 monomers and 0 to 50 wt.% other monomers, wherein the hydrocarbon resin has a Q of 0.015 [°C·mol/g] to 0.050 [°C·mol/g] according to formula I): I) Q = softening point [°C] / centrifuge medium Mz [g/mol], and - At least one solution-polymerized diene rubber.