Sacrificial Layer Top Removal for Precise Film Thickness Control

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Solution Overview

Problem

The existing methods for removing the upper part of a sacrificial layer in semiconductor manufacturing face challenges such as achieving precise film thickness, controlling thickness and depth, reducing variations, minimizing substrate damage, improving filling properties, and increasing manufacturing yield and efficiency.

Innovation Solution

A method involving the application of a sacrificial solution containing a polymer with an acid-dissociable protective group and a solvent, followed by contact with an acidic aqueous solution and a remover, to accurately remove the upper part of the sacrificial layer, thereby controlling film thickness and depth, and enhancing substrate processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If etch back is performed by dry etching or wet etching to obtain desired film thickness, then film thickness accuracy is improved, but processing time increases

Engineering Contradiction:
Improvefilm thickness accuracyVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The sacrificial layer is formed with a predetermined thickness that is intentionally greater than the final desired thickness. This preliminary over-formation allows subsequent selective removal to achieve the exact target thickness, eliminating the need for time-consuming iterative etching processes while maintaining high precision.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The upper part of the sacrificial layer is selectively removed through contact with acidic aqueous solution followed by remover application. This extraction of the excess portion enables precise thickness control without requiring extended processing times associated with conventional etching methods.

Inventive Principle:
Principle #2Taking out (Extraction)

2Manufacturing precision

If the sacrificial film is made highly resistant to etching or the type/concentration of chemical solution is optimized to reduce etching rate, then film thickness accuracy after etching back is improved, but processing time increases

Engineering Contradiction:
Improvefilm thickness accuracyVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The invention changes the chemical parameters of the sacrificial layer by using a polymer with acid-dissociable protective groups. This parameter change enables selective removal through acid treatment followed by remover application, achieving precise thickness control without requiring highly resistant materials that would extend processing time.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If the upper part of the sacrificial layer is removed to achieve desired film thickness, then film thickness control is improved, but variation in thickness and depth of removed upper part increases

Engineering Contradiction:
Improvefilm thickness controlVSAvoidvariation in thickness and depth
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The two-step removal process provides inherent feedback control. The acidic aqueous solution treatment first modifies the upper part of the sacrificial layer, and then the remover selectively removes the modified portion. This sequential approach allows precise control and minimizes variation in the removed thickness and depth, ensuring consistent results.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The removal process is segmented into two distinct stages: (1) treatment with acidic aqueous solution to modify the upper part, and (2) application of remover to selectively remove the modified portion. This segmentation enables better control over the removal process, reducing variations in thickness and depth compared to single-step methods.

Inventive Principle:
Principle #1Segmentation

4Productivity

If conventional methods are used to remove the upper part of the sacrificial layer, then manufacturing process is maintained, but substrate damage occurs

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidsubstrate damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The acidic aqueous solution acts as an intermediary that selectively modifies the upper part of the sacrificial layer without directly contacting or damaging the substrate. This intermediary treatment enables subsequent selective removal while protecting the substrate from damage, maintaining manufacturing efficiency without harmful side effects.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for precise control of film thickness and depth, reduces substrate damage, improves filling properties, and increases manufacturing yield and efficiency by accurately removing the sacrificial layer, leading to better electrical characteristics and simplified device manufacturing processes.

Implementation Method 1

a polymer having an acid-dissociable protective group (A)

Methodology Applied
Scientific EffectAcid dissociation: Hydrolysis

Implementation Method 2

subjecting an acidic aqueous solution to contact with the surface of the sacrificial layer

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 3

applying a remover to the sacrificial layer

Methodology Applied
Scientific EffectSelective dissolution: Solvation

Data Source

PatentUS20250014899A1Method for removing upper part of sacrificial layer, and sacrificial solution and acidic aqueous solution used therefor
Publication Date: 2025.01.09 MERCK PATENT GMBH
  • US20250014899A1 patent drawing
  • US20250014899A1 patent drawing
  • US20250014899A1 patent drawing

AI summary

[Problem] To provide a method for removing the upper part of a sacrificial layer. [Means for Solution] A method for removing the upper part of a sacrificial layer comprising the following steps: ·(1) applying a sacrificial solution comprising a polymer having an acid-dissociable protective group (A) and a solvent (B) above a substrate; ·(2) forming a sacrificial layer from the applied sacrificial solution; ·(3) subjecting an acidic aqueous solution to contact with the surface of the sacrificial layer; and ·(4) applying a remover to the sacrificial layer.