Lower Alkyl Esters for Saffron Odor Notes

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Solution Overview

Problem

Current perfumery lacks compounds that effectively impart saffron and spicy odor notes, with existing ingredients either lacking unique odor profiles or introducing unwanted floral or woody characteristics.

Innovation Solution

The use of lower alkyl esters of 4,6,6-trimethyl-1,3-cyclohexadiene-1-carboxylate or 4,6,6-trimethyl-3-cyclohexene-1-carboxylate, such as ethyl and methyl esters, which provide distinct spicy-saffron and rosy-like odor notes without floral or woody characteristics, are employed as perfuming ingredients.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If existing perfuming ingredients are used, then perfumes can be formulated, but they lack unique saffron and spicy odor notes or introduce unwanted floral and woody characteristics

Engineering Contradiction:
Improveavailability of perfuming ingredientsVSAvoidunwanted floral or woody odor characteristics
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by modifying the chemical structure of cyclohexene carboxylate esters - specifically changing the substitution pattern to 4,6,6-trimethyl and varying the alkyl group (methyl, ethyl, propyl, butyl) - to achieve a unique saffron-spicy odor profile that differs from prior art compounds and eliminates unwanted floral or woody characteristics

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If compounds with saffron odor notes are sought, then unique perfumery applications are enabled, but existing compounds either lack these notes or have unwanted characteristics

Engineering Contradiction:
Improveunique organoleptic impressions for perfumeryVSAvoidlack of pure saffron-spicy odor profile
Core Design Contradiction:
Adaptability or versatilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by specifically targeting the odor profile characteristics - achieving concentrated saffron and spicy notes at specific positions in the odor pyramid (head, heart, and base notes) while eliminating unwanted floral or woody characteristics in other positions, creating a pure and distinctive saffron-spicy fragrance identity

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS8222199B2Perfuming ingredients with saffron odor
Publication Date: 2012.07.17 FIRMENICH SA
  • US8222199B2 patent drawing
  • US8222199B2 patent drawing
  • US8222199B2 patent drawing

AI summary

The present invention concerns the use as perfuming ingredient of a lower alkyl ester of 4,6,6-trimethyl-1,3-cyclohexadiene-1-carboxylate or 4,6,6-trimethyl-3-cyclohexene-1-carboxylate. These compounds are able to impart odor notes of the spicy/saffron type.