Salt Cavern Hydrogen Storage Pressure Optimization

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Solution Overview

Problem

Storing very high purity hydrogen in underground salt caverns is challenging due to permeation issues and the limited pressure containment capacity, which poses safety and economic risks.

Innovation Solution

Maintaining very high purity hydrogen at pressures between 1.0 and 4.0 psi per linear foot within a salt cavern, using a method that includes solution mining with an inert gas blanket to form a stable roof and optimize cavern geometry, thereby creating a fundamentally impervious barrier to hydrogen leakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If hydrogen is stored at higher pressures to increase storage capacity, then storage efficiency improves, but hydrogen permeation through salt walls increases causing safety hazards

Engineering Contradiction:
Improvehydrogen storage capacityVSAvoidhydrogen permeation and leakage
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent changes the pressure parameter from the conventional limit of 1.0 psi/ft to a higher range of 1.0-4.0 psi/ft, demonstrating that with proper fracture control, higher pressures can be safely utilized to increase storage capacity while maintaining safety through monitored pressure management

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary fracture healing treatments (such as grouting or chemical injection) to seal potential leakage paths before hydrogen storage begins, preventing permeation issues before they can occur during high-pressure operation

Inventive Principle:
Principle #10Preliminary action

2Reliability

If salt caverns are used for hydrogen storage to avoid pipeline dependency, then supply security improves, but hydrogen permeation through salt formation creates safety risks

Engineering Contradiction:
Improvesupply securityVSAvoidhydrogen permeation through salt
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent performs preliminary fracture assessment and healing treatments during the cavern preparation phase, sealing potential permeation paths before hydrogen is introduced, thereby enabling safe long-term storage that maintains supply security

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces intermediary substances (such as grout or chemical sealants) into fracture zones to block hydrogen permeation paths, acting as a mediator between the hydrogen storage requirement and the salt formation's natural permeability issues

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If conventional pressure limits of 1.0 psi per foot are enforced to ensure safety, then hydrogen leakage is prevented, but storage capacity and economic efficiency are reduced

Engineering Contradiction:
Improvehydrogen leakage preventionVSAvoidstorage capacity and economic efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent revises the pressure parameter from the conservative 1.0 psi/ft limit to an optimized range extending to 4.0 psi/ft, based on demonstrated fracture healing capabilities and monitored safety protocols, thereby quadruppling potential storage capacity while maintaining acceptable safety margins

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements continuous monitoring of pressure, temperature, and potential leakage indicators, using this feedback to dynamically adjust operational parameters and maintain safe storage conditions at higher pressures that would otherwise be prohibited by conventional static limits

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases the storage capacity of hydrogen within the same physical volume, reducing leakage risks and improving economic efficiency by exceeding the conventional 1 psi per foot pressure limit, allowing for safer and more economical storage of high purity hydrogen.

Implementation Method 1

the salt cavern forms a substantially impermeable barrier to the stored very high purity hydrogen therein

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Implementation Method 2

the salt is significantly more prone to very high purity hydrogen permeation by virtue of hydrogen's small atomic radius

Methodology Applied
Scientific EffectPermeation resistance: Permeation

Data Source

PatentUS11167927B1Method for storing very high purity hydrogen in a salt cavern
Publication Date: 2021.11.09 AIR LIQUIDE LARGE IND US LP
  • US11167927B1 patent drawing
  • US11167927B1 patent drawing
  • US11167927B1 patent drawing

AI summary

A method for storing very high purity hydrogen in a salt cavern is provided. The method includes introducing a compressed very high purity hydrogen gas into a salt cavern, thereby producing a stored very high purity hydrogen gas; maintaining the stored very high purity hydrogen gas at a pressure greater than about 1.0 psi per linear foot of height within the cavern, and less than about 4.0 psi per linear foot of height within the cavern.