Self-Assembled Monolayer Blocking Layers for OLED Pixel Protection

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The manufacturing process of organic light-emitting display devices faces challenges in protecting intermediate layers during the formation of subsequent layers, leading to potential damage and reduced reliability of the final device.

Innovation Solution

A method involving the formation of self-assembled monolayer blocking layers, including fluorine-based and hydrocarbon-based polymers with organic-inorganic silane compounds, is used to cover and protect intermediate layers, preventing exposure and damage during subsequent processing stages.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional protective layers are used to cover intermediate layers during manufacturing, then the intermediate layers are protected from damage, but the binding strength between layers is insufficient and the process complexity increases

Engineering Contradiction:
Improveprotection of intermediate layersVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The blocking layer material performs dual functions: it protects the intermediate layer during manufacturing and provides strong binding for subsequent layers. The self-assembling nature of the material allows it to automatically form protective barriers without requiring complex external processing, making the protective function inherent to the material itself rather than an added complexity.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent changes the chemical and physical parameters of the blocking layer material by using self-assembling monolayers with specific functional groups. This transformation allows the material to exhibit both protective and binding properties simultaneously, resolving the contradiction between protection effectiveness and process simplicity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If multiple protective layers are formed sequentially for different pixel electrodes, then each intermediate layer is protected during its formation stage, but the manufacturing time and process steps increase

Engineering Contradiction:
Improveprotection during layer formationVSAvoidmanufacturing cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The blocking layer is formed preliminarily on the intermediate layer before subsequent processing steps. This preliminary protective action ensures that the intermediate layer is already protected when subsequent layers are formed, eliminating the need for additional protective measures during each manufacturing stage and reducing overall process time.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The blocking layer material serves multiple functions: protecting the intermediate layer, providing binding for subsequent layers, and enabling selective removal. This multi-functionality reduces the need for multiple specialized protective layers, thereby reducing manufacturing time and process complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If blocking layers are formed on all pixel electrodes, then comprehensive protection is achieved, but the flexibility to selectively process specific pixels is reduced

Engineering Contradiction:
Improvecomprehensive protectionVSAvoidselective processing capability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The blocking layer is formed with spatially varying properties: it is present on some pixel electrodes and absent on others, depending on the specific manufacturing requirements for each pixel type. This local differentiation allows comprehensive protection where needed while maintaining flexibility for selective processing, resolving the contradiction between uniform protection and adaptive processing.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the binding strength of protective layers and minimizes damage to intermediate layers, thereby increasing the reliability and efficiency of the organic light-emitting display device manufacturing process.

Implementation Method 1

each of the first blocking layer and the second blocking layer includes a self-assembled monolayer

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

a head group including an organic-inorganic silane compound

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 3

a chain including at least one of a fluorine-based polymer and a hydrocarbon-based polymer

Methodology Applied
Scientific EffectPolymer deposition: Deposition (physical)

Data Source

PatentUS10236328B2Method of manufacturing organic light-emitting display device
Publication Date: 2019.03.19 SAMSUNG DISPLAY CO LTD
  • US10236328B2 patent drawing
  • US10236328B2 patent drawing
  • US10236328B2 patent drawing

AI summary

A method of manufacturing an organic light-emitting display device includes forming pixel electrodes on a substrate, forming a first protective layer with a first exposure portion that exposes a first pixel electrode of the pixel electrodes, forming on the first pixel electrode a first intermediate layer and a first blocking layer covering the first intermediate layer, removing the first protective layer, forming a second protective with a second exposure portion that exposes a second pixel electrode of the pixel electrodes, forming on the first pixel electrode a second intermediate layer and a second blocking layer covering the second intermediate layer, removing the second protective layer, forming a third protective with a third exposure portion that exposes a third pixel electrode of the pixel electrodes, and forming a third intermediate layer on the third pixel electrode, wherein each of the first and second blocking layers includes a self-assembled monolayer.