SAMP Sensor Coating for Paraffin and Asphaltene Fouling

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Solution Overview

Problem

Current methods for preventing paraffin and asphaltene deposition on sensitive tank level sensors and instrumentation in crude oil service operations are labor-intensive, costly, and not very effective, posing safety hazards and leading to significant economic losses.

Innovation Solution

A nano-coating composition, specifically a Self-Assembled Monolayer of Phosphonate (SAMP), is applied to stainless steel and nickel alloy components to create a non-stick surface, reducing the affinity for paraffin and asphaltene deposits, thereby preventing their initial formation and ensuring long-term resistance in extreme petroleum production environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional cleaning and maintenance methods are used to remove paraffin and asphaltene deposits, then deposits can be removed, but the process is labor-intensive, costly, and requires shutdowns that reduce productivity

Engineering Contradiction:
Improvesensor reliabilityVSAvoidoperational continuity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The SAMP coating is applied in advance to sensor surfaces to create a protective barrier that prevents paraffin and asphaltene deposition before it occurs. This preliminary protective action eliminates the need for subsequent cleaning operations and maintains sensor reliability without requiring operational shutdowns.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The coating transforms the problematic interaction between crude oil deposits and sensor surfaces into a beneficial non-stick surface. By modifying the surface properties at the molecular level, the harmful deposition process is converted into a protective mechanism where deposits are prevented from adhering in the first place.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-affected harmful factors

If chemical treatments are applied to prevent deposition, then some protection is achieved, but chemical residues can interfere with sensor readings and create additional contamination problems

Engineering Contradiction:
Improvedeposition resistanceVSAvoidchemical contamination
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The SAMP coating acts as an intermediary layer between the crude oil environment and the sensor surface. This molecular barrier provides deposition resistance while being inert to sensor operations, preventing both external deposits and chemical contamination without interfering with sensor readings.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The monolayer coating provides a thin, lightweight protective barrier that is sufficient for its intended purpose of preventing deposition. The coating is applied as a molecular monolayer rather than thick chemical treatments, minimizing material usage and potential contamination while maintaining effectiveness.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of repair

If manual cleaning procedures are used, then deposits can be removed, but safety hazards are created for maintenance personnel and equipment downtime occurs

Engineering Contradiction:
Improvemaintenance accessibilityVSAvoidsafety hazards
Core Design Contradiction:
Ease of repairVSObject-affected harmful factors

Solution Approach 1:

The SAMP coating provides self-protecting properties to sensor surfaces, making them inherently resistant to paraffin and asphaltene deposition. This self-service mechanism eliminates the need for manual cleaning interventions, removing safety hazards for maintenance personnel while preventing equipment downtime.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The coating applies preliminary protection to sensor surfaces before exposure to crude oil deposits. By pre-establishing a non-stick surface property, the coating prevents the formation of hazardous deposit conditions that would otherwise require dangerous manual cleaning operations.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nano-coating significantly reduces paraffin and asphaltene deposition, enhancing sensor reliability, improving safety for maintenance personnel, and lowering remediation costs by creating a durable, low-surface tension surface that is resistant to deposition, even in low acidity and turbulence conditions.

Implementation Method 1

Self-Assembled Monolayer of Phosphonate (SAMP)

Methodology Applied
Scientific EffectSelf-Assembly: Self-Assembly

Implementation Method 2

The phosphonic acid reacts with the component surface through stable metal phosphorus bonds

Methodology Applied
Scientific EffectChemisorption: Chemisorption

Implementation Method 3

creating a durable, low-surface tension surface that is resistant to deposition

Methodology Applied
Scientific EffectSurface Tension: Surface Tension

Data Source

PatentUS10934497B2SAMP treatment method for a device utilized in a crude oil service operation, and method of installing said device
Publication Date: 2021.03.02 E9 TREATMENTS INC
  • US10934497B2 patent drawing
  • US10934497B2 patent drawing
  • US10934497B2 patent drawing

AI summary

A method for installing a device into a crude oil service operation, the method may include installing the device into a section of the crude oil service operation, wherein the device comprises a surface comprising a Self-Assembled Monolayer of Phosphonate (SAMP) coating, and may also include contacting the surface with the contaminant, wherein the contaminant is selected from the group consisting of paraffins and asphaltenes. Various systems include one having a liquid environment of paraffins and asphaltene, and a surface residing within the environment comprising a Self-Assembled Monolayer of Phosphonate (SAMP) composition. Systems also include pipelines and vessels having an internal surface therein comprising a Self-Assembled Monolayer of Phosphonate (SAMP) composition, and with hydrocarbon liquids present in the pipeline or vessel.