Sandwich Composite Coating on Engineering Plastic via PVD

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Solution Overview

Problem

Conventional dry coating methods for engineering plastics face issues such as environmental pollution, high water and energy consumption, use of toxic chemicals, poor corrosion and weather resistance, and difficulty in achieving a smooth, high-luster surface due to defects on the substrate.

Innovation Solution

A method involving dry cleaning and plasma gas glow activation of the plastic surface followed by the deposition of a metal basal film, an organic coating, and a secondary metal film using physical vapor deposition (PVD) techniques, eliminating the need for liquid water and toxic chemicals, and enhancing surface smoothness and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional wet plating technology is used to produce high corrosion and abrasion resistance with mirror-surface finish, then the surface quality and corrosion resistance are improved, but water consumption, energy consumption, and environmental pollution increase significantly

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The invention changes the fundamental parameters of the plating process from wet chemical methods to dry physical vapor deposition methods. This involves changing the phase state (from liquid to solid/vapor), the chemical environment (from aqueous to vacuum), and the deposition mechanism (from electrochemical to physical vapor deposition), thereby achieving mirror-surface finish and corrosion resistance without the associated water and energy consumption of conventional wet plating

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses vacuum environment as an inert atmosphere for the physical vapor deposition process. This vacuum environment prevents oxidation and contamination during metal film deposition, ensuring high corrosion resistance and mirror-surface quality while avoiding the need for large quantities of water and chemicals used in conventional wet plating

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Illumination intensity

If conventional wet plating technology is used to achieve metalized surface, then the surface luster and decoration are improved, but toxic chemicals and wastewater are produced

Engineering Contradiction:
Improvesurface lusterVSAvoidtoxic waste
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

The invention replaces the chemical-electrochemical system of wet plating with a physical vapor deposition system. Instead of using toxic chemical electrolytes and additives, the process uses physical evaporation and condensation of metals in a vacuum environment, thereby achieving mirror-surface luster without generating toxic waste chemicals or wastewater

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention converts the vacuum environment, which is typically used only for specialized applications, into a beneficial medium for green manufacturing. The vacuum serves dual purposes: enabling precise metal film deposition for mirror-surface quality and simultaneously preventing the formation of toxic chemicals, thereby converting a resource-intensive environment into an environmentally friendly process

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-generated harmful factors

If dry coating technology is used to substitute wet electroplating, then environmental pollution is reduced and production cost is lowered, but the coating has poor corrosion resistance and weather resistance

Engineering Contradiction:
Improveenvironmental pollutionVSAvoidcorrosion resistance
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention creates a composite coating structure consisting of multiple metal layers (such as aluminum base layer plus protective metal layer) deposited by physical vapor deposition. This composite structure combines the advantages of different materials: the aluminum layer provides corrosion resistance and adhesion, while the outer metal layer provides weather resistance and durability, all within an environmentally friendly dry process

Inventive Principle:
Principle #40Composite materials

4Loss of energy

If dry coating technology is used to achieve coating on plastic surface, then water consumption is reduced, but the binding force between layers is insufficient and surface smoothness is poor

Engineering Contradiction:
Improvewater consumptionVSAvoidsurface smoothness
Core Design Contradiction:
Loss of energyVSManufacturing precision

Solution Approach 1:

The invention applies preliminary surface treatment to the plastic substrate before metal deposition. This includes surface cleaning, activation, and roughening processes that prepare the plastic surface to enhance adhesion of the metal layers. By performing these preliminary actions, the process achieves strong interlayer binding and smooth surface finish without requiring water-intensive washing and treatment steps

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces a corrosion-resistant, abrasion-resistant, and weather-resistant metalized engineering plastic product with improved luster and reduced environmental impact, comparable to traditional wet electroplating in quality and cost-effectiveness.

Implementation Method 1

a plastic blank is dry cleaned and activated... the cleaned plastic blank is transferred into a physical vapor deposition (PVD) furnace and processed by a plasma gas glow activation

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

a metal basal film is formed on the activated plastic blank... using physical vapor deposition (PVD) techniques

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentEP2463031B1Method of preparing sandwich composite coating on engineering plastic surface
Publication Date: 2016.04.20 XIAMEN RUNNER IND CORP
  • EP2463031B1 patent drawingFigure 1

AI summary

A method of preparing a sandwich composite coating on an engineering plastic surface is provided to enhance the functions and quality of a plastic coated metal product, lowers the production cost, saves water (without requiring any water in the whole manufacturing process). The method includes the steps of dry cleaning and activating a plastic blank, placing the activated plastic blank into a PVD furnace, forming a metal basal film on the activated plastic blank, performing a plasma activation of the plastic blank with the metal basal film, sputtering an organic coating, and forming a metal coated film layer on the plastic blank placed into PVD furnace to produce a metalized engineering plastic product which is applicable for sanitary ware, electronics, electric appliances and in the automobile industry.