Superabsorbent Polymer Particle Distribution for Rapid Liquid Acquisition

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Solution Overview

Problem

Absorbent articles with superabsorbent polymer particles face challenges in achieving fast liquid acquisition, particularly at the initial contact with liquid, leading to potential leakage due to poor permeability and gel blocking, despite high Free Swell Rate (FSR) and Saline Flow Conductivity (SFC) values.

Innovation Solution

The absorbent article is designed with a structure comprising at least 90% superabsorbent polymer particles, optimized for a time to reach 20 g/g uptake of less than 440 seconds and enhanced permeability, featuring a thermoplastic adhesive material to immobilize particles and improve liquid distribution, reducing the risk of leakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If superabsorbent polymer particles with high Free Swell Rate (FSR) and high Saline Flow Conductivity (SFC) values are used, then absorption speed and permeability are improved, but fast acquisition time at initial liquid contact is not guaranteed

Engineering Contradiction:
Improveabsorption speedVSAvoidfast acquisition time at first gush
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the measurement parameter from equilibrium-based SFC to dynamic T20 acquisition time, capturing the initial absorption phase behavior. This parameter change reveals that high FSR and SFC do not correlate with fast initial acquisition, leading to optimized particle selections that specifically target first-gush performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by pre-swelling the superabsorbent polymer particles before use. This preliminary swelling action prepares the particles to rapidly acquire liquid at initial contact, addressing the slow first-gush acquisition problem while maintaining the benefits of high FSR and SFC particles

Inventive Principle:
Principle #10Preliminary action

2Productivity

If superabsorbent polymer particles absorb liquid quickly, then absorption capacity is improved, but gel blocking occurs and permeability decreases

Engineering Contradiction:
Improveabsorption capacityVSAvoidpermeability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies dynamics by measuring permeability under dynamic loading conditions rather than static equilibrium. The T20 measurement captures permeability behavior during the active absorption phase, revealing that particles maintaining high permeability during dynamic loading can achieve both high absorption capacity and sustained liquid flow without gel blocking

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent utilizes porous materials by selecting superabsorbent polymer particles with optimized pore structures that maintain open channels during swelling. This porous structure allows liquid to penetrate deeply and rapidly while preventing gel blocking, achieving both high absorption capacity and sustained permeability

Inventive Principle:
Principle #31Porous materials

3Quantity of substance

If absorbent core thickness is increased to improve absorption capacity, then liquid storage is improved, but liquid acquisition time increases

Engineering Contradiction:
Improveabsorption capacityVSAvoidliquid acquisition time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent applies local quality by creating a gradient in superabsorbent polymer particle distribution within the absorbent core. The region near the liquid entry point contains particles with optimized T20 characteristics for rapid initial acquisition, while deeper regions provide additional capacity. This local optimization ensures fast liquid capture without sacrificing overall absorption capacity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the absorbent core into functional zones with different particle characteristics. The top layer contains particles optimized for rapid liquid acquisition (low T20), while lower layers provide bulk absorption capacity. This segmentation allows the core to simultaneously achieve fast liquid capture and high storage capacity

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in improved absorption properties and reduced leakage, especially during the first gush, by ensuring fast and efficient liquid acquisition and distribution throughout the absorbent structure.

Implementation Method 1

Superabsorbent polymer particles are able to absorb liquid and swell when entering into contact with liquid exudates

Methodology Applied
Scientific EffectOsmosis: Osmosis

Implementation Method 2

The liquid exudates can not or only slowly reach underneath layers of superabsorbent polymer particles disposed in the core

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentEP2535698B1Absorbent article having improved absorption properties
Publication Date: 2023.12.06 PROCTER & GAMBLE CO
  • EP2535698B1 patent drawingFigure 1
  • EP2535698B1 patent drawingFigure 2
  • EP2535698B1 patent drawingFigure 3~4

AI summary

An absorbent article such as disposable diaper, training pant, and adult incontinence undergarment comprising an absorbent structure comprising superabsorbent polymer particles, the article being able to absorb and contain body exudates and having improved absorption properties and therefore being able to reduce leakage, especially at the first gush, i. e. when the article starts to be wetted.