SBAM Adsorbent Contactor Structures With Low Pressure Drop

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Solution Overview

Problem

Conventional contactor structures face challenges in achieving high adsorbent density and efficient fluid flow management, with packed beds causing pressure drops and monoliths limiting adsorption sites and temperature control.

Innovation Solution

Incorporating adsorbent particles into polymeric structures using solvent-based additive manufacturing (SBAM) to form continuous polymer structures with distributed adsorption sites, reducing pressure drops and enhancing adsorption capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If packed bed structures are used to incorporate large quantity of adsorbent, then adsorbent density is improved, but pressure drop increases

Engineering Contradiction:
Improveadsorbent densityVSAvoidpressure drop
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The packed bed is segmented into multiple smaller channels arranged in parallel, reducing the length and resistance of individual flow paths while maintaining overall adsorbent quantity. This segmentation allows fluid to distribute across multiple zones, lowering pressure drop per unit volume of adsorbent.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from a single-dimensional packed bed to a multi-channel monolith structure with three-dimensional flow distribution. By creating multiple parallel channels within the monolith, the system achieves higher adsorbent density while providing alternative flow paths that reduce pressure drop.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Object-generated harmful factors

If monolith structures are used to reduce pressure drop, then fluid flow efficiency is improved, but adsorbent site density is limited

Engineering Contradiction:
Improvepressure dropVSAvoidadsorbent site density
Core Design Contradiction:
Object-generated harmful factorsVSQuantity of substance

Solution Approach 1:

The monolith structure combines ceramic or metal support material with deposited adsorbent layers, creating a composite material system. This allows the structural integrity and flow channels of the monolith to be preserved while maximizing adsorbent loading on channel surfaces and within pores, increasing adsorbent site density without compromising fluid flow.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The monolith incorporates porous structures within its walls and channels, allowing adsorbent to be distributed throughout the volume rather than just on external surfaces. This porous architecture increases the available adsorbent site density while maintaining open flow paths that minimize pressure drop.

Inventive Principle:
Principle #31Porous materials

3Temperature

If complex structures are machined in ceramic or metal monoliths, then heat transfer fluid distribution is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveheat transfer fluid distributionVSAvoidmanufacturing complexity
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

Heat transfer fluid distribution channels are incorporated into the monolith structure during the manufacturing process itself, rather than requiring post-formation machining. This preliminary integration of thermal management features simplifies manufacturing by combining structure formation and fluid distribution channel creation in a single process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The monolith structure is designed to perform multiple functions simultaneously: providing mechanical support, defining process fluid flow channels, and incorporating heat transfer fluid distribution pathways. This multi-functionality reduces the need for separate machining operations and simplifies the overall manufacturing process.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

SBAM allows for the formation of polymeric structures with enhanced adsorption capacity and fluid flow efficiency, overcoming limitations of conventional designs by distributing adsorbent throughout the structure volume and minimizing fluid flow difficulties.

Implementation Method 1

after depositing a layer of ink, the polymeric structure is formed by phase inversion after evaporation of a portion of the solvent from the ink

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

the polymeric structure is formed by phase inversion after evaporation of a portion of the solvent from the ink

Methodology Applied
Scientific EffectPhase inversion: Phase Change

Implementation Method 3

use an adsorbent or absorbent to remove CO2 from a potential emission gas flow

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12497529B2Additive manufacturing techniques and ink formulations for incorporating adsorbent particles
Publication Date: 2025.12.16 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US12497529B2 patent drawing
  • US12497529B2 patent drawing

AI summary

Ink compositions are provided for using solvent-based additive manufacturing (SBAM) techniques to form contactor structures and/or structures for use in an adsorption or absorption contactor. Methods forming a contactor using SBAM are also provided. The ink compositions can include a substantial content of adsorbent particles to provide enhanced adsorption by a contactor. Metal organic framework (MOF) structures and zeotype framework structures are examples of types of adsorbent particles that can be incorporated into an ink composition for forming a contactor structure by SBAM. The ink can further include a polymeric component that can serve as the structural component of a polymeric structural material produced by the additive manufacturing method. Such a structural material can correspond to a polymeric material with incorporated adsorbent particles. In some aspects, the polymeric structural material and/or the adsorbent particles can have selectivity for adsorption of CO2 from a process fluid flow.