Scavenging Metal Billet for Corrosion Resistant Cladding

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing processes for producing corrosion-resistant metal products with stainless steel or nickel-chrome, nickel-copper, and copper-nickel alloy claddings face challenges due to oxidation issues at the interface between the cladding and the steel core, leading to inadequate bonding and potential product failure, along with inefficiencies in manufacturing and equipment requirements.

Innovation Solution

A billet design incorporating a mass of scavenging metal, such as aluminum, titanium, or magnesium, to actively remove oxidizing gases at the interface before the cladding reaches temperatures that form oxides, ensuring a strong bond between the steel core and the cladding, and using a closed housing to prevent external gas penetration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the cladding is heated to bonding temperature, then strong bonding between steel core and cladding is achieved, but oxidation of chrome, nickel or copper occurs at the interface

Engineering Contradiction:
Improvebond strengthVSAvoidoxidation
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

A mass of scavenging metal is placed in the billet before heating to react with and remove oxidizing gases from the interface region before the cladding reaches oxidation-prone temperatures. This preliminary action prevents oxide formation while maintaining bonding capability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The scavenging metal acts as an intermediary substance between the oxidizing atmosphere and the cladding metal. It preferentially reacts with oxygen and other oxidizing gases, preventing direct oxidation of the chrome, nickel or copper in the cladding while allowing thermal energy to pass through for bonding.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If scavenging metal is added to prevent oxidation, then bonding quality improves, but device complexity and manufacturing process become more complex

Engineering Contradiction:
Improvebond reliabilityVSAvoidbillet structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The scavenging metal is placed locally at specific positions within the billet (e.g., adjacent to the interface region) rather than uniformly distributed. This localized placement provides oxidation protection where it is most needed while minimizing additional complexity in the overall billet structure.

Inventive Principle:
Principle #3Local quality

3Productivity

If heating rate is increased to improve productivity, then manufacturing speed increases, but oxidation occurs more rapidly at the interface

Engineering Contradiction:
Improvemanufacturing speedVSAvoidoxidation rate
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The scavenging metal is positioned in advance to react with oxidizing gases before they can attack the cladding, even during rapid heating. This preliminary protective action allows faster heating rates to be used without proportionally increasing oxidation damage.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces oxidation at the interface, resulting in a strong and reliable bond between the steel core and the cladding, compatible with modern rolling mills, and reduces capital costs by simplifying the manufacturing process and equipment requirements.

Implementation Method 1

oxidation issues at the interface between the cladding and the steel core

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

scavenging metal, such as aluminum, titanium, or magnesium, to actively remove oxidizing gases at the interface

Methodology Applied
Scientific EffectChemical reaction: Redox Reactions

Implementation Method 3

using a closed housing to prevent external gas penetration

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentUS9005767B2Corrosion resistant metal products
Publication Date: 2015.04.14 CLADINOX INT LTD
  • US9005767B2 patent drawing
  • US9005767B2 patent drawing
  • US9005767B2 patent drawing

AI summary

A billet includes a solid steel body and an alloy cladding. The cladding may include a square tube in which the body is inserted with an interface at which the cladding becomes bonded to the body when the billet is heated and rolled or otherwise worked into a ferrous product. At least one element composed of a mass of finely divided scavenging aluminum, titanium or magnesium, is placed in the tube adjacent the body and separate from the interface. The elements are advantageously compressed into briquettes which scavenge oxygen from residual air at the interface to prevent oxidation of the cladding at the interface. The tube may be closed to prevent gases outside the billet from penetrating to the interface. Alternatively, reliance may be placed on the briquettes to scavenge oxygen from the residual air and also from atmospheric air and furnace gases before they can penetrate to the interface.