Screen Printed Electrochemical Sensor Electrode Manufacturing

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Solution Overview

Problem

The existing solution-based methods for manufacturing electrochemical gas sensors are costly, labor-intensive, and require multiple steps, which increases production costs and material expenses.

Innovation Solution

The use of screen printing technology to create electrochemical gas sensors by printing a catalyst slurry, including a binder and diluents, onto a PTFE membrane, followed by sintering, which reduces the number of steps and simplifies the manufacturing process while maintaining the necessary gas diffusion and electrochemical interface properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solution-based methods are used to manufacture electrodes, then the electrochemical gas sensor can be produced with proper catalyst distribution and PTFE membrane integration, but the manufacturing process becomes complex with many steps, increasing production costs and labor costs

Engineering Contradiction:
Improveelectrode performanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple separate manufacturing steps into a single integrated screen printing process. The catalyst slurry containing PTFE, catalyst particles, and binder is printed directly onto the membrane in one operation, eliminating the need for separate steps of catalyst dispersion, PTFE addition, flocculate formation, and multiple transfers. This merging of operations reduces process complexity while maintaining electrode performance.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The screen printing process serves multiple functions simultaneously: it deposits the catalyst, distributes the PTFE binder, forms the electrode structure, and creates the appropriate porosity pattern. This multi-functional approach replaces several specialized manufacturing steps with a single versatile printing process, reducing both complexity and cost.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Manufacturing precision

If solution-based methods with multiple steps are used, then proper electrode structure can be achieved, but production time and labor costs increase

Engineering Contradiction:
Improveelectrode structure qualityVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The catalyst slurry is prepared in advance with the correct composition of PTFE, catalyst particles, and binder, allowing for direct printing without intermediate processing steps. This preliminary preparation of the complete electrode material enables a single-step printing process that maintains structural quality while dramatically improving production efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the physical state and composition parameters of the electrode material by using a screen-printable slurry formulation with specific viscosity and particle size distribution. This parameter optimization allows the slurry to be directly printed and sintered into a functional electrode, eliminating multiple intermediate processing steps and improving productivity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If traditional solution-based manufacturing is used, then electrode functionality can be achieved, but material costs and production costs increase

Engineering Contradiction:
Improvesensor functionalityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs a disposable screen printing stencil that can be used multiple times but is ultimately discarded, replacing expensive and complex manufacturing equipment. The simple screen printing apparatus and disposable stencils significantly reduce capital equipment costs and manufacturing complexity while maintaining electrode functionality.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent replaces complex mechanical assembly processes with a printing-based approach. Instead of mechanically assembling catalyst layers, PTFE membranes, and supports through multiple transfer and pressing operations, the entire electrode structure is formed by screen printing the slurry and subsequent sintering, simplifying the manufacturing system and reducing costs.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a more cost-effective and efficient production method for electrochemical gas sensors, such as oxygen and carbon monoxide sensors, with improved productivity and performance by maximizing the interfaces between the catalyst, gas, and electrolyte, as demonstrated by the response time graphs for O2 and CO sensors.

Implementation Method 1

The printed element is then sintered at an elevated temperature to form an electrode

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS10908115B2Method of forming electrochemical gas sensor
Publication Date: 2021.02.02 HONEYWELL INTERNATIONAL INC
  • US10908115B2 patent drawing
  • US10908115B2 patent drawing
  • US10908115B2 patent drawing

AI summary

A gas detector includes an electrochemical gas sensor. The sensor includes a plurality of electrodes. At least one of the electrodes is formed of a catalyst/binder slurry which is halftone printed onto a substrate. The composite printed element and substrate are sintered to form the electrode.