Sulphur Cycle-Associated Denitrifying EBPR for Wastewater Sludge Reduction

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Solution Overview

Problem

Conventional biological nutrient removal processes for wastewater treatment result in high sludge production due to the reliance on organic carbon for electron flow, leading to costly and environmentally undesirable sludge disposal.

Innovation Solution

The Sulphur cycle-associated Denitrifying Enhanced Biological Phosphorus Removal (SD-EBPR) process utilizes sulphur compounds as electron carriers to minimize sludge production by integrating a sulphur cycle for phosphorus uptake and release, denitrification, and carbon oxidation, reducing the need for excess sludge handling and disposal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional biological nutrient removal processes use organic carbon for electron flow, then carbon oxidation and phosphorus removal are achieved, but high sludge production occurs

Engineering Contradiction:
Improvenutrient removal efficiencyVSAvoidsludge production
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent changes the electron carrier parameter from organic carbon to sulphur compounds (such as sulphate). This fundamental parameter change alters the biological metabolism pathway, allowing PAOs to use sulphur as an electron donor instead of organic carbon, thereby reducing sludge production while maintaining nutrient removal efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Sulphur compounds serve as an intermediary substance that mediates the electron transfer process. The sulphate is reduced to sulphide by PAOs, which then donates electrons for carbon oxidation and phosphorus uptake, replacing the traditional organic carbon intermediary and enabling minimal sludge production

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If heterotrophic carbon oxidation is used for phosphorus removal, then phosphorus uptake is achieved, but 40-50% of organic carbon is converted to CO2 and the rest to sludge

Engineering Contradiction:
Improvephosphorus removal rateVSAvoidorganic carbon conversion to sludge
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent changes the metabolic pathway parameter by introducing sulphate-reducing PAOs that use sulphate as an electron acceptor instead of oxygen. This creates an anaerobic metabolism pathway where organic carbon is not oxidized for energy, but rather preserved and used for phosphorus uptake, fundamentally changing the carbon fate from CO2/sludge production to phosphorus incorporation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent inverts the traditional EBPR metabolism sequence. Instead of aerobic carbon oxidation followed by anoxic phosphorus uptake, the system uses anaerobic sulphate reduction followed by phosphorus uptake using stored carbon, reversing the conventional oxygen-first approach and eliminating the need for carbon oxidation

Inventive Principle:
Principle #13The other way round (Inversion)

3Device complexity

If conventional biological processes are simplified without nitrogen removal, then process complexity is reduced, but sludge disposal remains costly and environmentally undesirable

Engineering Contradiction:
Improveprocess complexityVSAvoidsludge disposal impact
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the electron carrier parameter to sulphur compounds, which fundamentally alters the sludge production parameter. This single parameter change resolves the contradiction by enabling simplified processes to achieve minimal sludge production, eliminating the need for complex sludge management infrastructure

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The SD-EBPR process effectively achieves simultaneous removal of carbon, nitrogen, and phosphorus with minimal sludge production, reducing treatment costs and greenhouse gas emissions, and demonstrating improved operational efficiency compared to conventional methods.

Implementation Method 1

sulphur compounds as electron carriers to minimize sludge production by integrating a sulphur cycle for phosphorus uptake and release, denitrification, and carbon oxidation

Methodology Applied
Scientific EffectElectron transfer: Redox Reactions

Implementation Method 2

The sulphur is also used to convert phosphorus containing compounds to solid material for retention in sewage sludge

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 3

Oxygen is used to oxidize any ammonia present to nitrate and/or nitrite

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

The sulphur is then used to perform denitrification of nitrogen compounds

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS9919940B2Sulphur cycle-associated denitrifying enhanced biological phosphorus removal (SD-EBPR) utilizing sulphur compounds as electron carriers for biological nutrient removal of wastewater treatment
Publication Date: 2018.03.20 THE HONG KONG UNIV OF SCI & TECH
  • US9919940B2 patent drawing
  • US9919940B2 patent drawing
  • US9919940B2 patent drawing

AI summary

Sewage treatment is performed by using Sulphur to facilitate electron flow. A first cycle uses a sulphur composition having sulphur and/or sulphur compounds to transfer electrons from organic carbon to oxygen, nitrate and nitrite, and to convert phosphorus-containing compounds to solid material, which is retained in sewage sludge. The sulphur is further used to perform denitrification of nitrogen compounds. A further cycle uses oxygen to oxidize any ammonia present to nitrate and/or nitrite.